Fluorene- and Benzimidazole-Based Blue Light-Emitting Copolymers: Synthesis, Photophysical Properties, and PLED Applications
文献类型：期刊论文
| 作者 | Zhu, Haifeng1; Tong, Hui2; Gong, Yongyang1; Shao, Shiyang2; Deng, Chunmei3; Yuan, Wang Zhang1; Zhang, Yongming1 |
| 刊名 | JOURNAL OF POLYMER SCIENCE PART A-POLYMER CHEMISTRY
 |
| 出版日期 | 2012-06-01 |
| 卷号 | 50期号:11页码:2172-2181 |
| 关键词 | Benzimidazole Conjugated Polymers Copolymerization Light-emitting Diodes (Led) |
| ISSN号 | 0887-624X |
| DOI | 10.1002/pola.25984 |
| 英文摘要 | Blue light-emitting materials are receiving considerable academic and industrial interest due to their potential applications in optoelectronic devices. In this study, blue light-emitting copolymers based on 9,9'-dioctylfluorene and 2,2'-(1,4-phenylene)-bis(benzimidazole) moieties were synthesized through palladium-catalyzed Suzuki coupling reaction. While the copolymer consisting of unsubstituted benzimidazoles (PFBI0) is insoluble in common organic solvents, its counterpart with N-octyl substituted benzimidazoles (PFBI8) enjoys good solubility in toluene, tetrahydrofuran, dichloromethane (DCM), and chloroform. The PFBI8 copolymer shows good thermal stability, whose glass transition temperature and onset decomposition temperature are 103 and 428 degrees C, respectively. Its solutions emit blue light efficiently, with the quantum yield up to 99% in chloroform. The electroluminescence (EL) device of PFBI8 with the configuration of indium-tin oxide/poly(ethylenedioxythiophene):poly( styrene sulfonic acid)/PFBI8/1,3,5-tris(1-phenyl-1H-benzimidazole-2-yl) benzene/LiF/Al emits blue light with the maximum at 448 nm. Such unoptimized polymer light-emitting diode (PLED) exhibits a maximum luminance of 1534 cd/m(2) with the current efficiency and power efficiency of 0.67 cd/A and 0.20 lm/W, respectively. The efficient blue emission and good EL performance make PFBI8 promising for optoelectronic applications. (C) 2012 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 50: 2172-2181, 2012 |
| 语种 | 英语 |
| WOS记录号 | WOS:000303756100009 |
| 出版者 | WILEY-BLACKWELL |
| 源URL | [http://ir.iccas.ac.cn/handle/121111/48295]  |
| 专题 | 中国科学院化学研究所 |
| 通讯作者 | Zhang, Yongming |
| 作者单位 | 1.Shanghai Jiao Tong Univ, Sch Chem & Chem Engn, Shanghai 200240, Peoples R China 2.Chinese Acad Sci, Changchun Inst Appl Chem, State Key Lab Polymer Phys & Chem, Changchun 130022, Peoples R China 3.Chinese Chem Soc, Beijing 100190, Peoples R China |
| 推荐引用方式 GB/T 7714 | Zhu, Haifeng,Tong, Hui,Gong, Yongyang,et al. Fluorene- and Benzimidazole-Based Blue Light-Emitting Copolymers: Synthesis, Photophysical Properties, and PLED Applications[J]. JOURNAL OF POLYMER SCIENCE PART A-POLYMER CHEMISTRY,2012,50(11):2172-2181. |
| APA | Zhu, Haifeng.,Tong, Hui.,Gong, Yongyang.,Shao, Shiyang.,Deng, Chunmei.,...&Zhang, Yongming.(2012).Fluorene- and Benzimidazole-Based Blue Light-Emitting Copolymers: Synthesis, Photophysical Properties, and PLED Applications.JOURNAL OF POLYMER SCIENCE PART A-POLYMER CHEMISTRY,50(11),2172-2181. |
| MLA | Zhu, Haifeng,et al."Fluorene- and Benzimidazole-Based Blue Light-Emitting Copolymers: Synthesis, Photophysical Properties, and PLED Applications".JOURNAL OF POLYMER SCIENCE PART A-POLYMER CHEMISTRY 50.11(2012):2172-2181. |
入库方式： OAI收割
来源：化学研究所
浏览0
下载0
收藏0
其他版本
除非特别说明，本系统中所有内容都受版权保护，并保留所有权利。