Calixarene-Supported Polynuclear Cobalt(II) Cluster Complexes Tuned by Substitution Groups of the Second Bridging Ligands
文献类型：期刊论文
| 作者 | Liu, Cai-Ming; Zhang, De-Qing; Hao, Xiang; Zhu, Dao-Ben |
| 刊名 | EUROPEAN JOURNAL OF INORGANIC CHEMISTRY
 |
| 出版日期 | 2012-09-01 |
| 期号 | 26页码:4210-4217 |
| 关键词 | Calixarenes Cluster Compounds Cobalt n Ligands Magnetic Properties |
| ISSN号 | 1434-1948 |
| DOI | 10.1002/ejic.201200682 |
| 英文摘要 | A wheel-like dodecanuclear cobalt(II) cluster complex [Co12(TBSOC)4(5-NH2-tz)8(CH3OH)6]center dot 3H2O center dot 5CH3OH (1, 5-NH2-tzH = 5-amino-1H-tetrazole) and an irregular rod-like tetradecanuclear cobalt(II) cluster complex [Co14(OH)2(TBSOC)4(5-ph-tz)10(5-ph-tzH)2(CH3OH)2] center dot 16.5H2O center dot 2CH3OH(2, 5-ph-tzH = 5-phenyl-1H-tetrazole) were solvothermally synthesized by using p-tert-butylsulfonylcalix[4]arene (H4TBSOC) and 5-subst-1H-tetrazoles as ligands. Single-crystal X-ray diffraction analyses revealed that the 5-substituent groups of the 1H-tetrazole bridging ligands have asignificant influence on the structure of the polynuclear cobalt(II) cluster complexes: 1 shows a closed wheel-like structure whereas 2 an open rod-like structure. A magnetic investigation indicated that both complexes exhibit antiferromagnetic properties. |
| 语种 | 英语 |
| WOS记录号 | WOS:000308401600013 |
| 出版者 | WILEY-V C H VERLAG GMBH |
| 源URL | [http://ir.iccas.ac.cn/handle/121111/48341]  |
| 专题 | 中国科学院化学研究所 |
| 通讯作者 | Liu, Cai-Ming |
| 作者单位 | Chinese Acad Sci, Inst Chem, Ctr Mol Sci, Beijing Natl Lab Mol Sci, Beijing 100190, Peoples R China |
| 推荐引用方式 GB/T 7714 | Liu, Cai-Ming,Zhang, De-Qing,Hao, Xiang,et al. Calixarene-Supported Polynuclear Cobalt(II) Cluster Complexes Tuned by Substitution Groups of the Second Bridging Ligands[J]. EUROPEAN JOURNAL OF INORGANIC CHEMISTRY,2012(26):4210-4217. |
| APA | Liu, Cai-Ming,Zhang, De-Qing,Hao, Xiang,&Zhu, Dao-Ben.(2012).Calixarene-Supported Polynuclear Cobalt(II) Cluster Complexes Tuned by Substitution Groups of the Second Bridging Ligands.EUROPEAN JOURNAL OF INORGANIC CHEMISTRY(26),4210-4217. |
| MLA | Liu, Cai-Ming,et al."Calixarene-Supported Polynuclear Cobalt(II) Cluster Complexes Tuned by Substitution Groups of the Second Bridging Ligands".EUROPEAN JOURNAL OF INORGANIC CHEMISTRY .26(2012):4210-4217. |
入库方式： OAI收割
来源：化学研究所
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