Effect of annealing on the microstructure and mechanical properties of polypropylene with oriented shish-kebab structure
文献类型:期刊论文
作者 | Bai, Hongwei1; Deng, Hua1; Zhang, Qin1; Wang, Ke1; Fu, Qiang1; Zhang, Zhijie2; Men, Yongfeng2 |
刊名 | POLYMER INTERNATIONAL
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出版日期 | 2012-02-01 |
卷号 | 61期号:2页码:252-258 |
关键词 | Polypropylene Shish-kebab Annealing Molecular Orientation Toughness |
ISSN号 | 0959-8103 |
DOI | 10.1002/pi.3180 |
英文摘要 | Annealing is thought to be an effective method to promote chain rearrangement in semicrystalline polymers and improve their physical properties. However, little attention has been paid to the annealing of flow-oriented semicrystalline polymers despite its importance in polymer processing. In this work, the microstructural evolution of injection-moulded polypropylene with an oriented shish-kebab structure upon annealing has been explored with differential scanning calorimetry, small-angle X-ray scattering and scanning electron microscopy, Fourier transform infrared spectroscopy and dynamic mechanical analysis. The results show that annealing gives rise to a chain rearrangement in both the crystalline and amorphous phases. Accompanied by the growth and perfecting of the kebabs, relaxation of the initially oriented chains in the amorphous phase is observed. Then, the relationship between the structure and the resulting mechanical properties is established. (C) 2011 Society of Chemical Industry |
语种 | 英语 |
WOS记录号 | WOS:000298840000015 |
出版者 | WILEY-BLACKWELL |
源URL | [http://ir.iccas.ac.cn/handle/121111/48453] ![]() |
专题 | 中国科学院化学研究所 |
通讯作者 | Deng, Hua |
作者单位 | 1.Sichuan Univ, State Key Lab Polymer Mat Engn, Coll Polymer Sci & Engn, Chengdu 610065, Peoples R China 2.Chinese Acad Sci, Changchun Inst Appl Chem, State Key Lab Polymer Phys & Chem, Changchun 130022, Peoples R China |
推荐引用方式 GB/T 7714 | Bai, Hongwei,Deng, Hua,Zhang, Qin,et al. Effect of annealing on the microstructure and mechanical properties of polypropylene with oriented shish-kebab structure[J]. POLYMER INTERNATIONAL,2012,61(2):252-258. |
APA | Bai, Hongwei.,Deng, Hua.,Zhang, Qin.,Wang, Ke.,Fu, Qiang.,...&Men, Yongfeng.(2012).Effect of annealing on the microstructure and mechanical properties of polypropylene with oriented shish-kebab structure.POLYMER INTERNATIONAL,61(2),252-258. |
MLA | Bai, Hongwei,et al."Effect of annealing on the microstructure and mechanical properties of polypropylene with oriented shish-kebab structure".POLYMER INTERNATIONAL 61.2(2012):252-258. |
入库方式: OAI收割
来源:化学研究所
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