Construction of Self-Organized Hybrid Ion Channel Membrane and Cationic Transport Mechanism
文献类型：期刊论文
| 作者 | Zhang Xinxin1,2; Wang Lihua2,3; Yun Yanbin1 |
| 刊名 | ACTA CHIMICA SINICA
 |
| 出版日期 | 2012-01-28 |
| 卷号 | 70期号:2页码:170-176 |
| 关键词 | Self-organization Ion Channel Hybrid Membrane Cation |
| ISSN号 | 0567-7351 |
| 英文摘要 | A kind of compound which could form hybrid organic-inorganic material-3-(ureido-4-methoxyphenyl)propyltriethoxysilane was obtained from 3-isocyanatopropyltriethoxysilane and p-anisidine. The structure and the crystallinity of the compound were characterized by FT-IR, H-1 NMR, DSC, and XRD methods. According to the self-assembling property of the compound, the ion channel hybrid membrane with the homogeneous structure was obtained by blending the compound and polyvinyl alcohol (PVA). Next, the cation transport properties of the membrane were tested by our self-made device, and the transport mechanism was proposed. SEM revealed that the ion channel hybrid membrane was dense and defect free. The thickness of the membrane was 8 mu m from the SEM images of cross section. Five kinds of cations were chosen for membrane transport experiments. The results demonstrated that the self-organized hybrid ion channel membrane could transport monovalent Li+, Na+ and K+, which was attributed to the cation-pi interaction with the methoxyphenyl moiety. The process of alkali cationic transport across membrane was explained with the dissolution-diffusion mechanism. The results showed that the permeability of Li+, Na+ and K+ transport through the hybrid membrane followed the order PNa+ > PK+ > PLi+, which revealed that the self-organized hybrid ion channel membrane reported in this paper preferred to transport Na+. Besides the hybrid membrane could not transport divalent Ca2+ and Mg2+. The result can provide new membrane materials for the separation of monovalent ions and divalent ions. |
| 语种 | 英语 |
| WOS记录号 | WOS:000300118400010 |
| 出版者 | SCIENCE PRESS |
| 源URL | [http://ir.iccas.ac.cn/handle/121111/48569]  |
| 专题 | 中国科学院化学研究所 |
| 通讯作者 | Zhang Xinxin |
| 作者单位 | 1.Beijing Forestry Univ, Coll Environm Sci & Engn, Beijing 100083, Peoples R China 2.Chinese Acad Sci, Inst Chem, New Mat Lab, Beijing 100190, Peoples R China 3.Tianjin Polytech Univ, State Key Lab Hollow Fiber Membrane Mat & Proc, Tianjin 300160, Peoples R China |
| 推荐引用方式 GB/T 7714 | Zhang Xinxin,Wang Lihua,Yun Yanbin. Construction of Self-Organized Hybrid Ion Channel Membrane and Cationic Transport Mechanism[J]. ACTA CHIMICA SINICA,2012,70(2):170-176. |
| APA | Zhang Xinxin,Wang Lihua,&Yun Yanbin.(2012).Construction of Self-Organized Hybrid Ion Channel Membrane and Cationic Transport Mechanism.ACTA CHIMICA SINICA,70(2),170-176. |
| MLA | Zhang Xinxin,et al."Construction of Self-Organized Hybrid Ion Channel Membrane and Cationic Transport Mechanism".ACTA CHIMICA SINICA 70.2(2012):170-176. |
入库方式： OAI收割
来源：化学研究所
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