Photovoltaic Performance of Dye-Sensitized Solar Cells Based on Al-Doped TiO2 Thin Films
文献类型：期刊论文
| 作者 | Liu Qiu-Ping1,2,3; Huang Hui-Juan4; Zhou Yang1; Duan Yan-Dong3; Sun Qing-Wen3; Lin Yuan3 |
| 刊名 | ACTA PHYSICO-CHIMICA SINICA
 |
| 出版日期 | 2012-03-01 |
| 卷号 | 28期号:3页码:591-595 |
| 关键词 | Titanium Dioxide Al-doped Film Hydrothermal Method X-ray Photoelectron Spectroscopy Photovoltaic Performance Flat Band Potential |
| ISSN号 | 1000-6818 |
| DOI | 10.3866/PKU.WHXB201112161 |
| 英文摘要 | Al-doped TiO2 thin films were synthesized by the hydrothermal method. To prepare a working electrode, a TiO2 or AlTiO2 slurry was coated onto a fluorine-doped tin oxide glass substrate by the doctor blade method and the coated substrate was sintered at 450 degrees C. TiO2 and Al-doped TiO2 films were characterized by X-ray photoelectron spectroscopy (XPS), X-ray diffraction (XRD), scanning electron microscopy (SEM), and tested by the dye-sensitized solar cell (DSSCs) system. The influences of Al-doping on TiO2 crystal form and the photovoltaic performance of DSSCs were investigated. X-ray photoelectron spectroscopy (XPS) data indicate that the doped Al ions exist in the form of Al3+, and these ions play a role as e(-) or h(+) traps and reduce the e(-)/h(+) pair recombination rate. The corresponding Mott-Schottky plot indicates that the Al-doped TiO2 photoanode shifts the flat band potential positively. The positive shift of the flat band potential improves the driving force of injected electrons from the LUMO of the dye to the conduction band of TiO2. The Al-doped TiO2 thin film shows a photovoltaic efficiency of 6.48%, which is higher than that of the undoped TiO2 thin film (5.58%) and the short-circuit photocurrent density increases from 16.5 to 18.2 mA.cm(-2). |
| 语种 | 英语 |
| WOS记录号 | WOS:000301693800014 |
| 出版者 | PEKING UNIV PRESS |
| 源URL | [http://ir.iccas.ac.cn/handle/121111/48583]  |
| 专题 | 中国科学院化学研究所 |
| 通讯作者 | Zhou Yang |
| 作者单位 | 1.Beijing Jiaotong Univ, Sch Mech Elect & Control Engn, Beijing 100044, Peoples R China 2.Jiangxi Univ Sci & Technol, Coll Software, Nanchang 330013, Peoples R China 3.Chinese Acad Sci, Inst Chem, Beijing Natl Lab Mol Sci, Key Lab Photochem, Beijing 100190, Peoples R China 4.Jiujiang Vocat & Tech Coll, Jiujing 332000, Jiangxi, Peoples R China |
| 推荐引用方式 GB/T 7714 | Liu Qiu-Ping,Huang Hui-Juan,Zhou Yang,et al. Photovoltaic Performance of Dye-Sensitized Solar Cells Based on Al-Doped TiO2 Thin Films[J]. ACTA PHYSICO-CHIMICA SINICA,2012,28(3):591-595. |
| APA | Liu Qiu-Ping,Huang Hui-Juan,Zhou Yang,Duan Yan-Dong,Sun Qing-Wen,&Lin Yuan.(2012).Photovoltaic Performance of Dye-Sensitized Solar Cells Based on Al-Doped TiO2 Thin Films.ACTA PHYSICO-CHIMICA SINICA,28(3),591-595. |
| MLA | Liu Qiu-Ping,et al."Photovoltaic Performance of Dye-Sensitized Solar Cells Based on Al-Doped TiO2 Thin Films".ACTA PHYSICO-CHIMICA SINICA 28.3(2012):591-595. |
入库方式： OAI收割
来源：化学研究所
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