One-pot conversion of CO2 and glycerol to value-added products using propylene oxide as the coupling agent
文献类型：期刊论文
| 作者 | Ma, Jun; Song, Jinliang; Liu, Huizhen; Liu, Jinli; Zhang, Zhaofu; Jiang, Tao; Fan, Honglei; Han, Buxing |
| 刊名 | GREEN CHEMISTRY
 |
| 出版日期 | 2012 |
| 卷号 | 14期号:6页码:1743-1748 |
| ISSN号 | 1463-9262 |
| DOI | 10.1039/c2gc35150a |
| 英文摘要 | The effective conversion of carbon dioxide (CO2) and glycerol is an interesting topic in green chemistry. In this work, we studied the simultaneous transformation of CO2 and glycerol to value-added products using propylene oxide (PO) as coupling agent catalyzed by alkali metal halides. The effects of reaction temperature, CO2 pressure, reaction time, amount of catalyst, and PO to glycerol molar ratio on the reaction were investigated. It was discovered that the coupled catalytic reaction could produce glycerol carbonate (GC), propylene glycol (PG) and propylene carbonate (PC) very effectively using KI, an abundant and cheap salt, as the catalyst. The main reasons are that glycerol and PG are not only the reactant and product, respectively, but also act as the effective co-catalysts to promote the key step of the coupled reaction, and the reaction is thermodynamically favorable. This effective and atom economic route to convert glycerol and CO2 simultaneously has great potential application. |
| 语种 | 英语 |
| WOS记录号 | WOS:000304558500027 |
| 出版者 | ROYAL SOC CHEMISTRY |
| 源URL | [http://ir.iccas.ac.cn/handle/121111/48623]  |
| 专题 | 中国科学院化学研究所 |
| 通讯作者 | Ma, Jun |
| 作者单位 | Chinese Acad Sci, Inst Chem, Beijing Natl Lab Mol Sci, Beijing 100080, Peoples R China |
| 推荐引用方式 GB/T 7714 | Ma, Jun,Song, Jinliang,Liu, Huizhen,et al. One-pot conversion of CO2 and glycerol to value-added products using propylene oxide as the coupling agent[J]. GREEN CHEMISTRY,2012,14(6):1743-1748. |
| APA | Ma, Jun.,Song, Jinliang.,Liu, Huizhen.,Liu, Jinli.,Zhang, Zhaofu.,...&Han, Buxing.(2012).One-pot conversion of CO2 and glycerol to value-added products using propylene oxide as the coupling agent.GREEN CHEMISTRY,14(6),1743-1748. |
| MLA | Ma, Jun,et al."One-pot conversion of CO2 and glycerol to value-added products using propylene oxide as the coupling agent".GREEN CHEMISTRY 14.6(2012):1743-1748. |
入库方式： OAI收割
来源：化学研究所
浏览0
下载0
收藏0
其他版本
除非特别说明，本系统中所有内容都受版权保护，并保留所有权利。