Synthesis and Responsive Behavior of Amphiphilic PS-b-PEG Diblock Copolymer Brushes
文献类型：期刊论文
| 作者 | Yang Mu-Quan; Mao Jun; Dong Zhi-Xin; Wang Da-Peng; Ji Xiang-Ling |
| 刊名 | CHEMICAL JOURNAL OF CHINESE UNIVERSITIES-CHINESE
 |
| 出版日期 | 2012-12-10 |
| 卷号 | 33期号:12页码:2816-2821 |
| 关键词 | Polystyrene-b-polyethylene Glycol Diblock Copolymer Brush Atom Transfer Radical Polymerization Click Chemistry Responsive Behavior |
| ISSN号 | 0251-0790 |
| DOI | 10.7503/cjcu20120114 |
| 英文摘要 | Polystyrene-b-polyethylene glycol(PS-b-PEG) diblock copolymer brushes on a silicon wafer were synthesized via the combination of atom transfer radical polymerization(ATRP) and Click chemistry reaction. The ATRP initiator was grafted to silicon wafer. Then, polystyrene was grafted to the substrates through ATRP technique. After azidation with NaN3, the Si/SiO2/PS-Br brushes were transformed to Si/SiO2/PS-N-3 with azide groups at the ends. The synthesis of PS-b-PEG brushes was then achieved via the click reaction of the obtained Si/SiO2/PS-N-3 and an excess of alkynyl-PEG. The chemical compositions and the surface properties of the as-prepared PS-b-PEG brushes were detected via X-ray photoelectron spectroscopy(XPS), atomic force microscopy(AFM), ellipsometry, and water contact angle techniques. The responsive behavior of diblock copolymer brushes treated under different solvents was also discussed. |
| 语种 | 英语 |
| WOS记录号 | WOS:000313544300037 |
| 出版者 | HIGHER EDUCATION PRESS |
| 源URL | [http://ir.iccas.ac.cn/handle/121111/48683]  |
| 专题 | 中国科学院化学研究所 |
| 通讯作者 | Ji Xiang-Ling |
| 作者单位 | Chinese Acad Sci, Changchun Inst Appl Chem, State Key Lab Polymer Phys & Chem, Changchun 130022, Peoples R China |
| 推荐引用方式 GB/T 7714 | Yang Mu-Quan,Mao Jun,Dong Zhi-Xin,et al. Synthesis and Responsive Behavior of Amphiphilic PS-b-PEG Diblock Copolymer Brushes[J]. CHEMICAL JOURNAL OF CHINESE UNIVERSITIES-CHINESE,2012,33(12):2816-2821. |
| APA | Yang Mu-Quan,Mao Jun,Dong Zhi-Xin,Wang Da-Peng,&Ji Xiang-Ling.(2012).Synthesis and Responsive Behavior of Amphiphilic PS-b-PEG Diblock Copolymer Brushes.CHEMICAL JOURNAL OF CHINESE UNIVERSITIES-CHINESE,33(12),2816-2821. |
| MLA | Yang Mu-Quan,et al."Synthesis and Responsive Behavior of Amphiphilic PS-b-PEG Diblock Copolymer Brushes".CHEMICAL JOURNAL OF CHINESE UNIVERSITIES-CHINESE 33.12(2012):2816-2821. |
入库方式： OAI收割
来源：化学研究所
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