Reactive ladder-like poly(p-decyl anilino)silsesquioxane for functional material's precursor: Synthesis, characterization and functionalization
文献类型：期刊论文
| 作者 | Chen, Zhize1; Ren, Zhongjie2; Zhang, Jintao1; Fu, Wenxin1; Li, Zhibo1; Zhang, Rongben1 |
| 刊名 | REACTIVE & FUNCTIONAL POLYMERS
 |
| 出版日期 | 2012-08-01 |
| 卷号 | 72期号:8页码:503-508 |
| 关键词 | Ladder Polymer Macromonomers Polysiloxanes Self-assembly Si-n Bonds |
| ISSN号 | 1381-5148 |
| DOI | 10.1016/j.reactfunctpolym.2012.05.003 |
| 英文摘要 | A well-defined polysilsesquioxane with reactive Si-N bonds, poly(p-decyl anilino)silsesquioxane (PASQ), was successfully prepared using supramolecular template polymerization. The monomers 1,3-bis-(p-decyl anilino)-1,1,3,3-tetrachloro-disiloxanes first self-assembled into ladder superstructures (LSs) primarily through the synergistic interactions of hydrogen bonding and the van der Waals interactions, and then polymerized by adding water and triethylamine to produce a well-defined PASQ The LSs was fully characterized using vapor pressure osmometry (VPO), UV-vis spectroscopy and X-ray diffraction (XRD). NMR and XRD measurements revealed that the PASQ was a ladder polymer. The reactivity of PASQ was confirmed by its Si-N bond reacting with trimethylsilanol to form a ladder-like trimethylsiloxysilicate (LMQ). The ladder structure of LMQ was also thoroughly characterized, which further verified the ladder structural regularity of PASQ. (C) 2012 Elsevier Ltd. All rights reserved. |
| 语种 | 英语 |
| WOS记录号 | WOS:000306623300003 |
| 出版者 | ELSEVIER SCIENCE BV |
| 源URL | [http://ir.iccas.ac.cn/handle/121111/48687]  |
| 专题 | 中国科学院化学研究所 |
| 通讯作者 | Zhang, Rongben |
| 作者单位 | 1.Chinese Acad Sci, Inst Chem, Beijing Natl Lab Mol Sci, Beijing 100190, Peoples R China 2.Beijing Univ Chem Technol, State Key Lab Chem Resource Engn, Beijing 100029, Peoples R China |
| 推荐引用方式 GB/T 7714 | Chen, Zhize,Ren, Zhongjie,Zhang, Jintao,et al. Reactive ladder-like poly(p-decyl anilino)silsesquioxane for functional material's precursor: Synthesis, characterization and functionalization[J]. REACTIVE & FUNCTIONAL POLYMERS,2012,72(8):503-508. |
| APA | Chen, Zhize,Ren, Zhongjie,Zhang, Jintao,Fu, Wenxin,Li, Zhibo,&Zhang, Rongben.(2012).Reactive ladder-like poly(p-decyl anilino)silsesquioxane for functional material's precursor: Synthesis, characterization and functionalization.REACTIVE & FUNCTIONAL POLYMERS,72(8),503-508. |
| MLA | Chen, Zhize,et al."Reactive ladder-like poly(p-decyl anilino)silsesquioxane for functional material's precursor: Synthesis, characterization and functionalization".REACTIVE & FUNCTIONAL POLYMERS 72.8(2012):503-508. |
入库方式： OAI收割
来源：化学研究所
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