The effect of benzyl amine on the efficiency of the base-catalyzed transamination of alpha-keto esters
文献类型：期刊论文
| 作者 | Xue, Fazhen1; Xiao, Xiao1; Wang, Haining1; Shi, Yian1,2 |
| 刊名 | TETRAHEDRON
 |
| 出版日期 | 2012-08-26 |
| 卷号 | 68期号:34页码:6862-6867 |
| 关键词 | Transamination Base-catalyzed Benzyl Amine Alpha-keto Esters Alpha-amino Esters Enantioselective |
| ISSN号 | 0040-4020 |
| DOI | 10.1016/j.tet.2012.06.023 |
| 英文摘要 | This paper describes the effect of benzyl amine on the base-catalyzed transamination of alpha-keto esters. Among various benzyl amines examined, o-HOC6H4CH2NH2 was found to be highly effective for the reaction, affording a wide variety of alpha-amino esters in good yields. The o-OH group of the benzyl amine facilitates the transamination process likely via H-bond. Moderate enantiomeric excess was obtained for alpha-amino ester when a quinine derived catalyst was used. (C) 2012 Elsevier Ltd. All rights reserved. |
| 语种 | 英语 |
| WOS记录号 | WOS:000306981800010 |
| 出版者 | PERGAMON-ELSEVIER SCIENCE LTD |
| 源URL | [http://ir.iccas.ac.cn/handle/121111/48693]  |
| 专题 | 中国科学院化学研究所 |
| 通讯作者 | Shi, Yian |
| 作者单位 | 1.Chinese Acad Sci, Beijing Natl Lab Mol Sci, CAS Key Lab Mol Recognit & Funct, Inst Chem, Beijing 100190, Peoples R China 2.Colorado State Univ, Dept Chem, Ft Collins, CO 80523 USA |
| 推荐引用方式 GB/T 7714 | Xue, Fazhen,Xiao, Xiao,Wang, Haining,et al. The effect of benzyl amine on the efficiency of the base-catalyzed transamination of alpha-keto esters[J]. TETRAHEDRON,2012,68(34):6862-6867. |
| APA | Xue, Fazhen,Xiao, Xiao,Wang, Haining,&Shi, Yian.(2012).The effect of benzyl amine on the efficiency of the base-catalyzed transamination of alpha-keto esters.TETRAHEDRON,68(34),6862-6867. |
| MLA | Xue, Fazhen,et al."The effect of benzyl amine on the efficiency of the base-catalyzed transamination of alpha-keto esters".TETRAHEDRON 68.34(2012):6862-6867. |
入库方式： OAI收割
来源：化学研究所
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