2-Substituted 8-(2-benzhydrylarylimino)-5,6,7-trihydroquinoline-N,N ' nickel dichlorides: Synthesis, characterization and catalytic behavior towards ethylene
文献类型：期刊论文
| 作者 | Hou, Xiaohua2,3,4; Liang, Tongling2,3; Sun, Wen-Hua2,3 ; Redshaw, Carl1; Chen, Xia4
|
| 刊名 | JOURNAL OF ORGANOMETALLIC CHEMISTRY
 |
| 出版日期 | 2012-06-15 |
| 卷号 | 708页码:98-105 |
| 关键词 | Distorted Trigonal Bipyramidal Geometry Distorted Tetrahedral Geometry Ethylene Polymerization Ethylene Oligomerization 2-substituted 8-(2-benzhydrylarylimino)-5 6 7-trihydroquinoline-n n ' Nickel Dichloride |
| ISSN号 | 0022-328X |
| DOI | 10.1016/j.jorganchem.2012.02.031 |
| 英文摘要 | A series of 2-substituted 8-(2-benzhydrylarylimino)-5,6,7-trihydroquinolines (L) was synthesized and fully characterized, and their nickel chloride complexes, namely 2-substituted 8-(2benzhydrylarylimino)-5,6,7-trihydroquinoline-N,N' nickel dichlorides (LNiCl2), were prepared and characterized by FT-IR and elemental analysis. The structures of representative complexes were confirmed by single crystal X-ray crystallography, which revealed a distorted trigonal bipyramidal geometry at the metal for complexes Ni3 and Ni5 containing an additional solvent molecule, and a distorted tetrahedral geometry for the complex Ni8. Upon activation with methylaluminoxane (MAO), all nickel pre-catalysts showed good activity for ethylene polymerization and considerable activity for ethylene oligomerization. (C) 2012 Elsevier B.V. All rights reserved. |
| 语种 | 英语 |
| WOS记录号 | WOS:000302935900013 |
| 出版者 | ELSEVIER SCIENCE SA |
| 源URL | [http://ir.iccas.ac.cn/handle/121111/48707]  |
| 专题 | 中国科学院化学研究所 |
| 通讯作者 | Redshaw, Carl |
| 作者单位 | 1.Univ E Anglia, Sch Chem, Norwich NR4 7TJ, Norfolk, England 2.Chinese Acad Sci, Key Lab Engn Plast, Inst Chem, Beijing 100190, Peoples R China 3.Chinese Acad Sci, Beijing Natl Lab Mol Sci, Inst Chem, Beijing 100190, Peoples R China 4.Shanxi Univ, Sch Chem & Chem Engn, Taiyuan 030006, Peoples R China |
| 推荐引用方式 GB/T 7714 | Hou, Xiaohua,Liang, Tongling,Sun, Wen-Hua,et al. 2-Substituted 8-(2-benzhydrylarylimino)-5,6,7-trihydroquinoline-N,N ' nickel dichlorides: Synthesis, characterization and catalytic behavior towards ethylene[J]. JOURNAL OF ORGANOMETALLIC CHEMISTRY,2012,708:98-105. |
| APA | Hou, Xiaohua,Liang, Tongling,Sun, Wen-Hua,Redshaw, Carl,&Chen, Xia.(2012).2-Substituted 8-(2-benzhydrylarylimino)-5,6,7-trihydroquinoline-N,N ' nickel dichlorides: Synthesis, characterization and catalytic behavior towards ethylene.JOURNAL OF ORGANOMETALLIC CHEMISTRY,708,98-105. |
| MLA | Hou, Xiaohua,et al."2-Substituted 8-(2-benzhydrylarylimino)-5,6,7-trihydroquinoline-N,N ' nickel dichlorides: Synthesis, characterization and catalytic behavior towards ethylene".JOURNAL OF ORGANOMETALLIC CHEMISTRY 708(2012):98-105. |
入库方式： OAI收割
来源：化学研究所
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