Shear effects on crystallization behavior of poly(ethylene-co-octene) copolymers
文献类型:期刊论文
作者 | Wen, Huiying1,2; Li, Hua1,2; Xu, Shuyan2; Xiao, Shengling2; Li, Hongfei; Jiang, Shichun1; An, Lijia1; Wu, Zhonghua3 |
刊名 | JOURNAL OF POLYMER RESEARCH
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出版日期 | 2012 |
卷号 | 19期号:1 |
关键词 | Poly(Ethylene-co-octene) coPolymer Shear Induced Crystallization Ethylene Sequence Length Distribution Mesophase |
ISSN号 | 1022-9760 |
DOI | 10.1007/s10965-011-9801-5 |
英文摘要 | Crystallization behavior of sheared polymer melts of a series of poly(ethylene-co-octene)s with different octene content was investigated by different scanning calorimetry (DSC), wide angle X-ray diffraction (WAXD) and synchrotron small-angle X-ray scattering (SR-SAXS) techniques. The DSC results indicated that the hexyl branches content had dramatic effects on the thermal properties and crystallinity of polyethylene. It was also found that shear had no obvious effects on the size of either crystallite or lamellae. However, both crystallite and lamellae were oriented by shearing, especially for the lamellae. All obtained results indicate that the initial states of the polymer melt play an important role in affecting the crystallization behaviors. The difference of the shear-induced crystalline structure evolution and the orientation between crystallite and lamellae support the preordered mesomorphic phase of flexible polymer crystallization process proposed by Strobl. |
语种 | 英语 |
WOS记录号 | WOS:000300772600012 |
出版者 | SPRINGER |
源URL | [http://ir.iccas.ac.cn/handle/121111/48713] ![]() |
专题 | 中国科学院化学研究所 |
通讯作者 | Jiang, Shichun |
作者单位 | 1.Chinese Acad Sci, Changchun Inst Appl Chem, State Key Lab Polymer Phys & Chem, Changchun 130022, Peoples R China 2.NE Forestry Univ, Heilongjiang Prov Key Lab, Harbin 150040, Peoples R China 3.Chinese Acad Sci, Inst High Energy Phys, Beijing Synchrotron Radiat Lab, Beijing 100039, Peoples R China |
推荐引用方式 GB/T 7714 | Wen, Huiying,Li, Hua,Xu, Shuyan,et al. Shear effects on crystallization behavior of poly(ethylene-co-octene) copolymers[J]. JOURNAL OF POLYMER RESEARCH,2012,19(1). |
APA | Wen, Huiying.,Li, Hua.,Xu, Shuyan.,Xiao, Shengling.,Li, Hongfei.,...&Wu, Zhonghua.(2012).Shear effects on crystallization behavior of poly(ethylene-co-octene) copolymers.JOURNAL OF POLYMER RESEARCH,19(1). |
MLA | Wen, Huiying,et al."Shear effects on crystallization behavior of poly(ethylene-co-octene) copolymers".JOURNAL OF POLYMER RESEARCH 19.1(2012). |
入库方式: OAI收割
来源:化学研究所
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