中国科学院机构知识库网格
Chinese Academy of Sciences Institutional Repositories Grid
Shear effects on crystallization behavior of poly(ethylene-co-octene) copolymers

文献类型:期刊论文

作者Wen, Huiying1,2; Li, Hua1,2; Xu, Shuyan2; Xiao, Shengling2; Li, Hongfei; Jiang, Shichun1; An, Lijia1; Wu, Zhonghua3
刊名JOURNAL OF POLYMER RESEARCH
出版日期2012
卷号19期号:1
关键词Poly(Ethylene-co-octene) coPolymer Shear Induced Crystallization Ethylene Sequence Length Distribution Mesophase
ISSN号1022-9760
DOI10.1007/s10965-011-9801-5
英文摘要Crystallization behavior of sheared polymer melts of a series of poly(ethylene-co-octene)s with different octene content was investigated by different scanning calorimetry (DSC), wide angle X-ray diffraction (WAXD) and synchrotron small-angle X-ray scattering (SR-SAXS) techniques. The DSC results indicated that the hexyl branches content had dramatic effects on the thermal properties and crystallinity of polyethylene. It was also found that shear had no obvious effects on the size of either crystallite or lamellae. However, both crystallite and lamellae were oriented by shearing, especially for the lamellae. All obtained results indicate that the initial states of the polymer melt play an important role in affecting the crystallization behaviors. The difference of the shear-induced crystalline structure evolution and the orientation between crystallite and lamellae support the preordered mesomorphic phase of flexible polymer crystallization process proposed by Strobl.
语种英语
WOS记录号WOS:000300772600012
出版者SPRINGER
源URL[http://ir.iccas.ac.cn/handle/121111/48713]  
专题中国科学院化学研究所
通讯作者Jiang, Shichun
作者单位1.Chinese Acad Sci, Changchun Inst Appl Chem, State Key Lab Polymer Phys & Chem, Changchun 130022, Peoples R China
2.NE Forestry Univ, Heilongjiang Prov Key Lab, Harbin 150040, Peoples R China
3.Chinese Acad Sci, Inst High Energy Phys, Beijing Synchrotron Radiat Lab, Beijing 100039, Peoples R China
推荐引用方式
GB/T 7714
Wen, Huiying,Li, Hua,Xu, Shuyan,et al. Shear effects on crystallization behavior of poly(ethylene-co-octene) copolymers[J]. JOURNAL OF POLYMER RESEARCH,2012,19(1).
APA Wen, Huiying.,Li, Hua.,Xu, Shuyan.,Xiao, Shengling.,Li, Hongfei.,...&Wu, Zhonghua.(2012).Shear effects on crystallization behavior of poly(ethylene-co-octene) copolymers.JOURNAL OF POLYMER RESEARCH,19(1).
MLA Wen, Huiying,et al."Shear effects on crystallization behavior of poly(ethylene-co-octene) copolymers".JOURNAL OF POLYMER RESEARCH 19.1(2012).

入库方式: OAI收割

来源:化学研究所

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