Synthesis, characterization and ethylene polymerization behavior of nickel dihalide complexes bearing bulky unsymmetrical alpha-diimine ligands
文献类型：期刊论文
| 作者 | Liu, Hao1,2,4; Zhao, Weizhen1,2; Yu, Jiangang1,2; Yang, Wenhong1,2; Hao, Xiang1,2; Redshaw, Carl3; Chen, Langqiu4; Sun, Wen-Hua1,2
|
| 刊名 | CATALYSIS SCIENCE & TECHNOLOGY
 |
| 出版日期 | 2012 |
| 卷号 | 2期号:2页码:415-422 |
| ISSN号 | 2044-4753 |
| DOI | 10.1039/c1cy00319d |
| 英文摘要 | A series of nickel(II) dihalide complexes (C1-C10) bearing unsymmetrical alpha-diimine ligands of the type 2,4-dibenzhydryl-N-(2-phenyliminoacenaphthylenylidene)-6-methylbenzenamine (L1-L5) were synthesized and fully characterized. Single-crystal X-ray diffraction revealed a distorted tetrahedral geometry around the nickel center in the complexes C3, C5 and C9. Upon activation with modified methylaluminoxane (MMAO), all nickel pro-catalysts performed with high activities in ethylene polymerization, producing highly branched polyethylene products. |
| 语种 | 英语 |
| WOS记录号 | WOS:000299291000025 |
| 出版者 | ROYAL SOC CHEMISTRY |
| 源URL | [http://ir.iccas.ac.cn/handle/121111/48733]  |
| 专题 | 中国科学院化学研究所 |
| 通讯作者 | Liu, Hao |
| 作者单位 | 1.Chinese Acad Sci, Inst Chem, Key Lab Engn Plast, Beijing 100190, Peoples R China 2.Chinese Acad Sci, Inst Chem, Beijing Natl Lab Mol Sci, Beijing 100190, Peoples R China 3.Univ E Anglia, Sch Chem, Norwich NR4 7TJ, Norfolk, England 4.Xiangtan Univ, Coll Chem, Key Lab Environm Friendly Chem & Applicat, Minist Educ, Xiangtan 411105, Peoples R China |
| 推荐引用方式 GB/T 7714 | Liu, Hao,Zhao, Weizhen,Yu, Jiangang,et al. Synthesis, characterization and ethylene polymerization behavior of nickel dihalide complexes bearing bulky unsymmetrical alpha-diimine ligands[J]. CATALYSIS SCIENCE & TECHNOLOGY,2012,2(2):415-422. |
| APA | Liu, Hao.,Zhao, Weizhen.,Yu, Jiangang.,Yang, Wenhong.,Hao, Xiang.,...&Sun, Wen-Hua.(2012).Synthesis, characterization and ethylene polymerization behavior of nickel dihalide complexes bearing bulky unsymmetrical alpha-diimine ligands.CATALYSIS SCIENCE & TECHNOLOGY,2(2),415-422. |
| MLA | Liu, Hao,et al."Synthesis, characterization and ethylene polymerization behavior of nickel dihalide complexes bearing bulky unsymmetrical alpha-diimine ligands".CATALYSIS SCIENCE & TECHNOLOGY 2.2(2012):415-422. |
入库方式： OAI收割
来源：化学研究所
浏览0
下载0
收藏0
其他版本
除非特别说明，本系统中所有内容都受版权保护，并保留所有权利。