中国科学院机构知识库网格
Chinese Academy of Sciences Institutional Repositories Grid
Characterization of high melt strength propylene/1-butene copolymer synthesized by in situ heat induction melt reaction

文献类型:期刊论文

作者An, Yanjie1,2; Xing, Haiping1; Wang, Yanhui1; Tang, Tao1
刊名JOURNAL OF APPLIED POLYMER SCIENCE
出版日期2012-08-15
卷号125期号:4页码:2724-2731
关键词Crosslinking Melt Strength Reactive Processing Polypropylene
ISSN号0021-8995
DOI10.1002/app.36591
英文摘要Propylene/1-butene copolymer powders were produced through bulk copolymerization of propylene with 1-butene in a 12 m3 polymerization reactor. High melt strength polypropylene (HMSPP) was synthesized by in situ heat induction melt reaction, in which pure propylene/1-butene copolymer powders without any additives were used as a basic resin and trimethylolpropane triacrylate (TMPTA) as a crosslinking agent. The structure and properties of the resultant HMSPP were characterized by means of various measurements. The content of TMPTA strongly influenced the melt strength and melt flow rate (MFR) of HMSPP. With increasing the content of TMPTA, the melt strength of HMSPP increased, and the MFR reduced. In addition, owing to the existence of crosslinking structure, thermal stability and tensile strength of HMSPP were improved compared with pristine propylene/1-butene copolymer. (C) 2012 Wiley Periodicals, Inc. J Appl Polym Sci, 2012
语种英语
WOS记录号WOS:000303596200028
出版者WILEY-BLACKWELL
源URL[http://ir.iccas.ac.cn/handle/121111/48849]  
专题中国科学院化学研究所
通讯作者Tang, Tao
作者单位1.Chinese Acad Sci, Changchun Inst Appl Chem, State Key Lab Polymer Phys & Chem, Changchun 130022, Peoples R China
2.Daqing Petrochem Res Ctr, Petrochem Res Inst, Daqing 163714, Peoples R China
推荐引用方式
GB/T 7714
An, Yanjie,Xing, Haiping,Wang, Yanhui,et al. Characterization of high melt strength propylene/1-butene copolymer synthesized by in situ heat induction melt reaction[J]. JOURNAL OF APPLIED POLYMER SCIENCE,2012,125(4):2724-2731.
APA An, Yanjie,Xing, Haiping,Wang, Yanhui,&Tang, Tao.(2012).Characterization of high melt strength propylene/1-butene copolymer synthesized by in situ heat induction melt reaction.JOURNAL OF APPLIED POLYMER SCIENCE,125(4),2724-2731.
MLA An, Yanjie,et al."Characterization of high melt strength propylene/1-butene copolymer synthesized by in situ heat induction melt reaction".JOURNAL OF APPLIED POLYMER SCIENCE 125.4(2012):2724-2731.

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来源:化学研究所

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