The properties, morphology and structure of BPDA/PPD/BOA polyimide fibers
文献类型：期刊论文
| 作者 | Huang, Senbiao1,2; Gao, Zhongmin3; Ma, Xiaoye1; Qiu, Xuepeng1; Gao, Lianxun1 |
| 刊名 | E-POLYMERS
 |
| 出版日期 | 2012-09-06 |
| ISSN号 | 1618-7229 |
| 英文摘要 | A family of random copoly(amic acid)s (coPAAs) containing the 2-(4-aminophenyl)-5- aminobenzoxazole (BOA) moiety were synthesized in DMAc, followed by dry-jet wet spinning process into as-spun PAA fibers. The modified polyimide (PI) fibers were obtained from PAA fibers after imidized and drawn in a furnace. The mechanical properties of fibers were improved by incorporating BOA into BPDA/PPD backbone. SEM photo showed that the cross-section of each stage fibers was round and voids free. Besides, the "skin-core" and microfibrillar structure were not observed. The thermal properties of PI fibers were also investigated. The results showed that the PI fibers owned excellent thermal stability, moreover, the dimensional stability and the microphase separation of fibers were improved by heat-drawn stage. The T-g were found to be around 290 degrees C by TMA and DMA. The X-ray (WAXD and SAXS) experiments indicated that the longitudinal stacks, the molecular orientation and the structural homogeneity of PI fiber were improved in the preparation process of fibers. |
| 语种 | 英语 |
| WOS记录号 | WOS:000308666900008 |
| 出版者 | EUROPEAN POLYMER FEDERATION |
| 源URL | [http://ir.iccas.ac.cn/handle/121111/48879]  |
| 专题 | 中国科学院化学研究所 |
| 通讯作者 | Huang, Senbiao |
| 作者单位 | 1.Chinese Acad Sci, Changchun Inst Appl Chem, State Key Lab Polymer Phys & Chem, Changchun 130022, Peoples R China 2.Chinese Acad Sci, Grad Univ, Beijing 100039, Peoples R China 3.Jilin Univ, State Key Lab Inorgan Synth & Preparat Chem, Changchun 130012, Peoples R China |
| 推荐引用方式 GB/T 7714 | Huang, Senbiao,Gao, Zhongmin,Ma, Xiaoye,et al. The properties, morphology and structure of BPDA/PPD/BOA polyimide fibers[J]. E-POLYMERS,2012. |
| APA | Huang, Senbiao,Gao, Zhongmin,Ma, Xiaoye,Qiu, Xuepeng,&Gao, Lianxun.(2012).The properties, morphology and structure of BPDA/PPD/BOA polyimide fibers.E-POLYMERS. |
| MLA | Huang, Senbiao,et al."The properties, morphology and structure of BPDA/PPD/BOA polyimide fibers".E-POLYMERS (2012). |
入库方式： OAI收割
来源：化学研究所
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