A novel melting behavior of poly(3-alkylthiophene) cocrystals: premelting and recrystallization of component polymers
文献类型：期刊论文
| 作者 | Qu, Yunpeng1,2,3; Li, Ligui1,2,3; Lu, Guanghao1,2,3; Zhou, Xun1,2,3; Su, Qing1,2; Xu, Wentao1,2,3; Li, Sijun1,2,3; Zhang, Jidong2; Yang, Xiaoniu1,2 |
| 刊名 | POLYMER CHEMISTRY
 |
| 出版日期 | 2012-12-01 |
| 卷号 | 3期号:12页码:3301-3307 |
| ISSN号 | 1759-9954 |
| DOI | 10.1039/c2py20400b |
| 英文摘要 | Poly(3-hexylthiophene) (P3HT) and poly(3-butylthiophene) (P3BT) cocrystals were prepared by solution casting and the cocrystals show two endothermic peaks in a differential scanning calorimetry (DSC) thermogram. The former endothermic peak is nearly fixed at the melting temperature of pure P3HT, while the latter one shifts gradually towards the P3BT melting point with increased P3BT content. This melting behavior of the polymer cocrystal is novel and different from the studies commonly reported in which the polymer cocrystal generally has one endothermic peak. After extensive analyses, including powder X-ray diffraction (XRD), synchrotron-based two dimensional grazing-incidence XRD, temperature-dependent UV-Visible spectroscopy and temperature modulated DSC, we propose the melting mechanism of P3HT/P3BT cocrystals involving three steps. In the first step, the P3HT component melts at the former endothermic peak around 241 degrees C. After that, the P3BT component recrystallizes when the coil-like P3HT chains escape from the cocrystal lattices. Finally, the P3BT component completely melts at the latter endothermic peak. These findings are beneficial to the understanding of the criteria for the formation and the melting behavior of polymer cocrystals. |
| 语种 | 英语 |
| WOS记录号 | WOS:000311328800017 |
| 出版者 | ROYAL SOC CHEMISTRY |
| 源URL | [http://ir.iccas.ac.cn/handle/121111/48895]  |
| 专题 | 中国科学院化学研究所 |
| 通讯作者 | Yang, Xiaoniu |
| 作者单位 | 1.Chinese Acad Sci, Changchun Inst Appl Chem, Polymer Composites Engn Lab, Changchun 130022, Peoples R China 2.Chinese Acad Sci, Changchun Inst Appl Chem, State Key Lab Polymer Phys & Chem, Changchun 130022, Peoples R China 3.Chinese Acad Sci, Grad Sch, Beijing 100049, Peoples R China |
| 推荐引用方式 GB/T 7714 | Qu, Yunpeng,Li, Ligui,Lu, Guanghao,et al. A novel melting behavior of poly(3-alkylthiophene) cocrystals: premelting and recrystallization of component polymers[J]. POLYMER CHEMISTRY,2012,3(12):3301-3307. |
| APA | Qu, Yunpeng.,Li, Ligui.,Lu, Guanghao.,Zhou, Xun.,Su, Qing.,...&Yang, Xiaoniu.(2012).A novel melting behavior of poly(3-alkylthiophene) cocrystals: premelting and recrystallization of component polymers.POLYMER CHEMISTRY,3(12),3301-3307. |
| MLA | Qu, Yunpeng,et al."A novel melting behavior of poly(3-alkylthiophene) cocrystals: premelting and recrystallization of component polymers".POLYMER CHEMISTRY 3.12(2012):3301-3307. |
入库方式： OAI收割
来源：化学研究所
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