Manipulating the Crystallization of Methanofullerene Thin Films with Polymer Additives
文献类型：期刊论文
| 作者 | Zheng, Lidong1,2; Liu, Jiangang1; Sun, Yue1,2; Ding, Yan1,2; Han, Yanchun1 |
| 刊名 | MACROMOLECULAR CHEMISTRY AND PHYSICS
 |
| 出版日期 | 2012-10-15 |
| 卷号 | 213期号:19页码:2081-2090 |
| 关键词 | Additives Crystallizing Kinetics Fullerenes Spherulites |
| ISSN号 | 1022-1352 |
| DOI | 10.1002/macp.201200341 |
| 英文摘要 | Trace amount (1% to 5%) of polymers [polystyrene (PS), poly(methyl methacrylate) (PMMA), and poly(3-hexylthiophene) (P3HT)] are utilized as additives to manipulate the cold crystallization of [6,6]-phenyl-C61 butyric acid methyl ester (PCBM) thin films. Highly crystalline PCBM films made up of well-connected domains and isolated spherulites with tunable size are produced by adjusting the type, molecular weight, and amount of polymer additives. In the nucleation stage, the polymer additives are demonstrated to have a depressing effect on PCBM nucleation. In the growth stage, we suggest that the PCBM growth rate is determined by PCBM molecular diffusion, which is demonstrated to have close correlations with the molecular mobility and crystallinity of the polymer. |
| 语种 | 英语 |
| WOS记录号 | WOS:000309449800012 |
| 出版者 | WILEY-V C H VERLAG GMBH |
| 源URL | [http://ir.iccas.ac.cn/handle/121111/48907]  |
| 专题 | 中国科学院化学研究所 |
| 通讯作者 | Han, Yanchun |
| 作者单位 | 1.Chinese Acad Sci, Changchun Inst Appl Chem, State Key Lab Polymer Phys & Chem, Changchun 130022, Peoples R China 2.Chinese Acad Sci, Grad Univ, Changchun 130022, Peoples R China |
| 推荐引用方式 GB/T 7714 | Zheng, Lidong,Liu, Jiangang,Sun, Yue,et al. Manipulating the Crystallization of Methanofullerene Thin Films with Polymer Additives[J]. MACROMOLECULAR CHEMISTRY AND PHYSICS,2012,213(19):2081-2090. |
| APA | Zheng, Lidong,Liu, Jiangang,Sun, Yue,Ding, Yan,&Han, Yanchun.(2012).Manipulating the Crystallization of Methanofullerene Thin Films with Polymer Additives.MACROMOLECULAR CHEMISTRY AND PHYSICS,213(19),2081-2090. |
| MLA | Zheng, Lidong,et al."Manipulating the Crystallization of Methanofullerene Thin Films with Polymer Additives".MACROMOLECULAR CHEMISTRY AND PHYSICS 213.19(2012):2081-2090. |
入库方式： OAI收割
来源：化学研究所
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