Hydrogenation of methyl laurate to produce lauryl alcohol over Cu/ZnO/Al2O3 with methanol as the solvent and hydrogen source
文献类型：期刊论文
| 作者 | Liang, Shuguang; Liu, Huizhen; Liu, Jinli; Wang, Weitao; Jiang, Tao; Zhang, Zhaofu; Han, Buxing |
| 刊名 | PURE AND APPLIED CHEMISTRY
 |
| 出版日期 | 2012 |
| 卷号 | 84期号:3页码:779-788 |
| 关键词 | Cu/zno/al2o3 Heterogeneous Catalysis Hydrogenation Lauryl Alcohol Methanol Methyl Laurate Supercritical Fluids |
| ISSN号 | 0033-4545 |
| DOI | 10.1351/PAC-CON-11-06-09 |
| 英文摘要 | Hydrogenation of methyl laurate was conducted over a Cu/ZnO/Al2O3 catalyst, using methanol as the solvent and hydrogen source, to give lauryl alcohol. In this process, the solvent underwent partial decomposition in contact with the catalyst to generate hydrogen, which served as the hydrogenation agent. The effect of different factors on the reaction was examined, to optimize production of lauryl alcohol with high conversion efficiency and selectivity. Use of methanol as the solvent not only favored the reaction, but also suppressed a side reaction involving transesterification between methyl laurate and lauryl alcohol. Under optimal reaction conditions, 91.8 % conversion of methyl laurate and 88.8 % yield of lauryl alcohol could be achieved. |
| 语种 | 英语 |
| WOS记录号 | WOS:000301282100027 |
| 出版者 | INT UNION PURE APPLIED CHEMISTRY |
| 源URL | [http://ir.iccas.ac.cn/handle/121111/48977]  |
| 专题 | 中国科学院化学研究所 |
| 通讯作者 | Jiang, Tao |
| 作者单位 | Chinese Acad Sci, Inst Chem, Beijing Natl Lab Mol Sci, Beijing 100190, Peoples R China |
| 推荐引用方式 GB/T 7714 | Liang, Shuguang,Liu, Huizhen,Liu, Jinli,et al. Hydrogenation of methyl laurate to produce lauryl alcohol over Cu/ZnO/Al2O3 with methanol as the solvent and hydrogen source[J]. PURE AND APPLIED CHEMISTRY,2012,84(3):779-788. |
| APA | Liang, Shuguang.,Liu, Huizhen.,Liu, Jinli.,Wang, Weitao.,Jiang, Tao.,...&Han, Buxing.(2012).Hydrogenation of methyl laurate to produce lauryl alcohol over Cu/ZnO/Al2O3 with methanol as the solvent and hydrogen source.PURE AND APPLIED CHEMISTRY,84(3),779-788. |
| MLA | Liang, Shuguang,et al."Hydrogenation of methyl laurate to produce lauryl alcohol over Cu/ZnO/Al2O3 with methanol as the solvent and hydrogen source".PURE AND APPLIED CHEMISTRY 84.3(2012):779-788. |
入库方式： OAI收割
来源：化学研究所
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