Investigation of N-Hexadecylated Poly (p-Phenylene Terephthamide) by Infrared Spectroscopy
文献类型：期刊论文
| 作者 | Kong Lei1; Li Rong-bo1; Zhao Ying1; Shi Hai-feng2; Wang Du-jin1; Xu Duan-fu1; Wi Jin-guang3 |
| 刊名 | SPECTROSCOPY AND SPECTRAL ANALYSIS
 |
| 出版日期 | 2012-10-01 |
| 卷号 | 32期号:10页码:2647-2650 |
| 关键词 | Poly(P-phenylene Terephthamide) N-alkylation Infrared Spectroscopy Side Chain Crystallization Thermal Analysis |
| ISSN号 | 1000-0593 |
| DOI | 10.3964/j.issn.1000-0593(2012)10-2647-04 |
| 英文摘要 | N-hexadecylated poly(p-phenylene terephthamide) (PPTA) comb-like polymers (PPTAC16), which are composed of PPTA backbone and hexadecyl side chains, were prepared by method of N-alkylation reaction. The molecular structure and thermal transition behavior of PPTAC16 were characterized by a combination of differential scanning calorimetry (DSC) and Fourier transform infrared spectroscopy (FT-W) technique. DSC results indicated that the crystallization of hexadecyl side chains, and the side chain crystallization is less perfect than that of n-hexadecane crystal. IR results showed that the ordered degree of the packing of CH(2)w group in the side chain crystallization is lower than that of n-hexadecane crystal. Variable temperature IR spectroscopic results revealed that the stretching vibration and bending vibration bands of methylene group experience an abrupt change with increasing of temperature which indicate the melting of the side chain crystallization, furthermore the main chain of PPTAC16 was found to undergo an irreversible change accompanying the melting of the alkyl side chain crystallization. And the molten state of CH2 group in the hexadecyl of PPTAC16 is different from that of liquid n-hexadecane. |
| 语种 | 英语 |
| WOS记录号 | WOS:000309798600013 |
| 出版者 | OFFICE SPECTROSCOPY & SPECTRAL ANALYSIS |
| 源URL | [http://ir.iccas.ac.cn/handle/121111/48999]  |
| 专题 | 中国科学院化学研究所 |
| 通讯作者 | Zhao Ying |
| 作者单位 | 1.Chinese Acad Sci, Inst Chem, Key Lab Engn Plast, Beijing 100190, Peoples R China 2.Tianjin Polytech Univ, Inst Funct Fibers, Coll Mat Sci & Engn, Tianjin 300387, Peoples R China 3.Peking Univ, Coll Chem & Mol Engn, Beijing 100871, Peoples R China |
| 推荐引用方式 GB/T 7714 | Kong Lei,Li Rong-bo,Zhao Ying,et al. Investigation of N-Hexadecylated Poly (p-Phenylene Terephthamide) by Infrared Spectroscopy[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS,2012,32(10):2647-2650. |
| APA | Kong Lei.,Li Rong-bo.,Zhao Ying.,Shi Hai-feng.,Wang Du-jin.,...&Wi Jin-guang.(2012).Investigation of N-Hexadecylated Poly (p-Phenylene Terephthamide) by Infrared Spectroscopy.SPECTROSCOPY AND SPECTRAL ANALYSIS,32(10),2647-2650. |
| MLA | Kong Lei,et al."Investigation of N-Hexadecylated Poly (p-Phenylene Terephthamide) by Infrared Spectroscopy".SPECTROSCOPY AND SPECTRAL ANALYSIS 32.10(2012):2647-2650. |
入库方式： OAI收割
来源：化学研究所
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