Synthesis and characterizations of poly(4-alkylthiazole vinylene)
文献类型：期刊论文
| 作者 | Guo, Xia1,2,3; Fan, Haijun3; Zhang, Maojie3; Huang, Yu3; Tan, Songting1,2; Li, Yongfang3 |
| 刊名 | JOURNAL OF APPLIED POLYMER SCIENCE
 |
| 出版日期 | 2012-04-05 |
| 卷号 | 124期号:1页码:847-854 |
| 关键词 | Conjugated Polymers Poly(Thiazole Vinylene) Bandgap Polymer Solar Cells Synthesis |
| ISSN号 | 0021-8995 |
| DOI | 10.1002/app.35106 |
| 英文摘要 | Two poly(thiazole vinylene) derivatives, poly(4-hexylthiazole vinylene) (P4HTzV) and poly(4-nonylthiazole vinylene) (P4NTzV), were synthesized by Pd-catalyzed Stille coupling method. The polymers are soluble in common organic solvents such as o-dichlorobenzene and chloroform, and possess good thermal stability. P4HTzV and P4NTzV films exhibit broad absorption bands at 400720 nm with an optical bandgap of 1.77 eV and 1.74 eV, respectively. The HOMO (the highest occupied molecular orbital) energy levels of P4HTzV and P4NTzV are -5.11 and -5.12 eV, respectively, measured by cyclic voltammetry. Preliminary results of the polymer solar cells based on P4HTzV : PC61BM ([6,6]-phenyl-C-61-butyric acid methyl ester) (1 : 1, w/w) show a power conversion efficiency of 0.21% with an open-circuit voltage of 0.55 V and a short circuit current density of 1.11 mA cm(-2), under the illumination of AM1.5G, 100 mW cm(-2). (C) 2011 Wiley Periodicals, Inc. J Appl Polym Sci, 2012 |
| 语种 | 英语 |
| WOS记录号 | WOS:000298637300096 |
| 出版者 | WILEY-BLACKWELL |
| 源URL | [http://ir.iccas.ac.cn/handle/121111/49065]  |
| 专题 | 中国科学院化学研究所 |
| 通讯作者 | Tan, Songting |
| 作者单位 | 1.Xiangtan Univ, Coll Chem, Key Lab Adv Funct Polymer Mat Hunan Prov, Xiangtan 411105, Peoples R China 2.Xiangtan Univ, Key Lab Environm Friendly Chem & Applicat, Minist Educ, Xiangtan 411105, Peoples R China 3.Chinese Acad Sci, Inst Chem, CAS Key Lab Organ Solids, Beijing 100190, Peoples R China |
| 推荐引用方式 GB/T 7714 | Guo, Xia,Fan, Haijun,Zhang, Maojie,et al. Synthesis and characterizations of poly(4-alkylthiazole vinylene)[J]. JOURNAL OF APPLIED POLYMER SCIENCE,2012,124(1):847-854. |
| APA | Guo, Xia,Fan, Haijun,Zhang, Maojie,Huang, Yu,Tan, Songting,&Li, Yongfang.(2012).Synthesis and characterizations of poly(4-alkylthiazole vinylene).JOURNAL OF APPLIED POLYMER SCIENCE,124(1),847-854. |
| MLA | Guo, Xia,et al."Synthesis and characterizations of poly(4-alkylthiazole vinylene)".JOURNAL OF APPLIED POLYMER SCIENCE 124.1(2012):847-854. |
入库方式： OAI收割
来源：化学研究所
浏览0
下载0
收藏0
其他版本
除非特别说明，本系统中所有内容都受版权保护，并保留所有权利。