中国科学院机构知识库网格
Chinese Academy of Sciences Institutional Repositories Grid
Hygroscopicity of internally mixed aerosol particles containing benzoic acid and inorganic salts

文献类型:期刊论文

作者Shi, Yajun1,2; Ge, Maofa1; Wang, Weigang1
刊名ATMOSPHERIC ENVIRONMENT
出版日期2012-12-01
卷号60页码:9-17
关键词Hygroscopicity Benzoic Acid H-tdma Internal Mixture Inorganic Salts
ISSN号1352-2310
DOI10.1016/j.atmosenv.2012.06.034
英文摘要The hygroscopic behaviors of benzoic acid (BA) particles and internal mixtures of inorganic salts (sodium chloride and ammonium sulfate) and BA are investigated in the 10-90% RH using the hygroscopicity tandem differential mobility analyzer (H-TDMA) system. Different morphology of BA. NaCl-BA, and (NH4)(2)SO4 BA particles at representative RH is characterized by Transmission Electron Microscopy (TEM). The hygroscopic growth factors (GFs) of BA exhibit a significant reduction in the 75-85% RH, followed by a slight increase at 90% RH. Internally mixed NaCl-BA and (NH4)(2)SO4 BA particles display deliquescence transitions at 70% RH, followed by apparently hampered hygroscopic growth due to the presence of BA. According to the TEM results, the morphology of BA particles and mixed particles show marked change in humidification, which possibly can be attributed to the strong microstructural rearrangement of BA fraction. This significant restructuring is responsible for the GFs change of BA particles and the hygroscopic behaviors transformation of mixed NaCl-BA and (NH4)(2)SO4-BA particles. These results demonstrate that atmospheric BA could significantly influence the hygroscopic properties of inorganic aerosols. (c) 2012 Elsevier Ltd. All rights reserved.
语种英语
WOS记录号WOS:000309789800002
出版者PERGAMON-ELSEVIER SCIENCE LTD
源URL[http://ir.iccas.ac.cn/handle/121111/49103]  
专题中国科学院化学研究所
通讯作者Ge, Maofa
作者单位1.Chinese Acad Sci, Inst Chem, State Key Lab Struct Chem Unstable & Stable Speci, Beijing Natl Lab Mol Sci, Beijing 100190, Peoples R China
2.Chinese Acad Sci, Grad Univ, Beijing 100039, Peoples R China
推荐引用方式
GB/T 7714
Shi, Yajun,Ge, Maofa,Wang, Weigang. Hygroscopicity of internally mixed aerosol particles containing benzoic acid and inorganic salts[J]. ATMOSPHERIC ENVIRONMENT,2012,60:9-17.
APA Shi, Yajun,Ge, Maofa,&Wang, Weigang.(2012).Hygroscopicity of internally mixed aerosol particles containing benzoic acid and inorganic salts.ATMOSPHERIC ENVIRONMENT,60,9-17.
MLA Shi, Yajun,et al."Hygroscopicity of internally mixed aerosol particles containing benzoic acid and inorganic salts".ATMOSPHERIC ENVIRONMENT 60(2012):9-17.

入库方式: OAI收割

来源:化学研究所

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