Facile synthesis of 1-bromo-7-alkoxyl perylene diimide dyes: toward unsymmetrical functionalizations at the 1,7-positions
文献类型：期刊论文
| 作者 | Zhang, Xin1,3; Pang, Shufeng1; Zhang, Zhigang2,3; Ding, Xunlei4; Zhang, Shanlin3; He, Shenggui4; Zhan, Chuanlang3 |
| 刊名 | TETRAHEDRON LETTERS
 |
| 出版日期 | 2012-02-29 |
| 卷号 | 53期号:9页码:1094-1097 |
| 关键词 | Perylene Diimide Nucleophilic Substitution Unsymmetrical Functionalization Nucleophile |
| ISSN号 | 0040-4039 |
| DOI | 10.1016/j.tetlet.2011.12.080 |
| 英文摘要 | In this Letter, we report a facile approach to synthesize unsymmetrical 1-bromo-7-alkoxyl perylene diimides by the nucleophilic substitution of one of the two 1.7-dibromo units with an alkyl alcohol using K2CO3 as the base. A further replacement of another bromo, for example, by using 4-hydroxylpyridine resulted in unsymmetrical functionalizations at the 1,7-positions. The optical properties of the unsymmetrical PDI derivative were reported and compared with those of the symmetrical derivative. (C) 2011 Elsevier Ltd. All rights reserved. |
| 语种 | 英语 |
| WOS记录号 | WOS:000301833600023 |
| 出版者 | PERGAMON-ELSEVIER SCIENCE LTD |
| 源URL | [http://ir.iccas.ac.cn/handle/121111/49185]  |
| 专题 | 中国科学院化学研究所 |
| 通讯作者 | Pang, Shufeng |
| 作者单位 | 1.Beijing Inst Technol, Sch Chem, Beijing 100081, Peoples R China 2.Hebei Normal Univ Sci & Technol, Qinhuangdao 066004, Hebei, Peoples R China 3.Chinese Acad Sci, Beijing Natl Lab Mol Sci, Lab Photochem, Inst Chem, Beijing 100190, Peoples R China 4.Chinese Acad Sci, Beijing Natl Lab Mol Sci, State Key Lab Struct Chem Unstable & Stable Speci, Inst Chem, Beijing 100080, Peoples R China |
| 推荐引用方式 GB/T 7714 | Zhang, Xin,Pang, Shufeng,Zhang, Zhigang,et al. Facile synthesis of 1-bromo-7-alkoxyl perylene diimide dyes: toward unsymmetrical functionalizations at the 1,7-positions[J]. TETRAHEDRON LETTERS,2012,53(9):1094-1097. |
| APA | Zhang, Xin.,Pang, Shufeng.,Zhang, Zhigang.,Ding, Xunlei.,Zhang, Shanlin.,...&Zhan, Chuanlang.(2012).Facile synthesis of 1-bromo-7-alkoxyl perylene diimide dyes: toward unsymmetrical functionalizations at the 1,7-positions.TETRAHEDRON LETTERS,53(9),1094-1097. |
| MLA | Zhang, Xin,et al."Facile synthesis of 1-bromo-7-alkoxyl perylene diimide dyes: toward unsymmetrical functionalizations at the 1,7-positions".TETRAHEDRON LETTERS 53.9(2012):1094-1097. |
入库方式： OAI收割
来源：化学研究所
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