Solution-Processed and Air-Stable n-Type Organic Thin-Film Transistors Based on Thiophene-Fused Dicyanoquinonediimine (DCNQI) Deriatives
文献类型:期刊论文
作者 | Chen, Shiyan1; Zhao, Yan2; Bolag, Altan3; Nishida, Jun-ichi3; Liu, Yunqi2; Yamashita, Yoshiro3 |
刊名 | ACS APPLIED MATERIALS & INTERFACES
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出版日期 | 2012-08-01 |
卷号 | 4期号:8页码:3994-4000 |
关键词 | Thiophene-fused Dcnqi N-type Solution-processed Air-stable Organic Thin-film Transistors |
ISSN号 | 1944-8244 |
DOI | 10.1021/am300822z |
英文摘要 | pi-Conjugated systems 2a and 2b containing thiophene-fused DCNQI with long alkyl and trifluoromethylphenyl groups were synthesized as potential active materials for solution processed and air stable n-type organic thin-film transistors (OTFTs). The electrochemical measurements revealed that the lowest unoccupied molecular orbital (LUMO) of the, compounds have an energy level less than -4.0 eV, indicating air stable n-type materials. The long alkyl groups endowed the a compounds good solubility and solution-processability. X-ray diffraction measurements revealed the difference of the molecular arrangement depending on the alkyl groups, which were also observed in the UV-vis absorptions of the films. A relatively good mobility up to 0.003 cm(2) V-1 s(-1) for 2a by spin-coating was obtained with good air stability. |
语种 | 英语 |
WOS记录号 | WOS:000307698600033 |
出版者 | AMER CHEMICAL SOC |
源URL | [http://ir.iccas.ac.cn/handle/121111/49187] ![]() |
专题 | 中国科学院化学研究所 |
通讯作者 | Chen, Shiyan |
作者单位 | 1.Donghua Univ, Coll Mat Sci & Engn, State Key Lab Modificat Chem Fibers & Polymer Mat, Key Lab Text Sci & Technol,Minist Educ, Shanghai 201620, Peoples R China 2.Chinese Acad Sci, Beijing Natl Lab Mol Sci, Key Lab Organ Solids, Inst Chem, Beijing 100190, Peoples R China 3.Tokyo Inst Technol, Interdisciplinary Grad Sch Sci & Engn, Dept Elect Chem, Midori Ku, Yokohama, Kanagawa 2268502, Japan |
推荐引用方式 GB/T 7714 | Chen, Shiyan,Zhao, Yan,Bolag, Altan,et al. Solution-Processed and Air-Stable n-Type Organic Thin-Film Transistors Based on Thiophene-Fused Dicyanoquinonediimine (DCNQI) Deriatives[J]. ACS APPLIED MATERIALS & INTERFACES,2012,4(8):3994-4000. |
APA | Chen, Shiyan,Zhao, Yan,Bolag, Altan,Nishida, Jun-ichi,Liu, Yunqi,&Yamashita, Yoshiro.(2012).Solution-Processed and Air-Stable n-Type Organic Thin-Film Transistors Based on Thiophene-Fused Dicyanoquinonediimine (DCNQI) Deriatives.ACS APPLIED MATERIALS & INTERFACES,4(8),3994-4000. |
MLA | Chen, Shiyan,et al."Solution-Processed and Air-Stable n-Type Organic Thin-Film Transistors Based on Thiophene-Fused Dicyanoquinonediimine (DCNQI) Deriatives".ACS APPLIED MATERIALS & INTERFACES 4.8(2012):3994-4000. |
入库方式: OAI收割
来源:化学研究所
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