Rhenium Complexes of 2,3-Di(2-pyridyl)-5,6-diphenylpyrazine: Synthesis, Characterization, and Reactivity
文献类型：期刊论文
| 作者 | Wu, Si-Hai1; Abruna, Hector D.2; Zhong, Yu-Wu1 |
| 刊名 | ORGANOMETALLICS
 |
| 出版日期 | 2012-02-13 |
| 卷号 | 31期号:3页码:1161-1167 |
| ISSN号 | 0276-7333 |
| DOI | 10.1021/om201240c |
| 英文摘要 | The reaction of 2,3-di(2-pyridyl)-5,6-diphenylpyrazine (dpdpz) with Re(CO)(5)Cl in acetonitrile or toluene afforded mono-Re and bis-Re complexes [Re(CO)(3)Cl-dpdpz] and [Re(CO)(3)Cl-dpdpz-Re(CO)(3)Cl], respectively. A heterodinuclear complex [Ru(bpy)(2)-dpdpz-Re(CO)(3)Cl](PF6)(2) could be prepared by the reaction of [Re(CO)(3)Cl-dpdpz] with Ru(bpy)(2)Cl-2 or the reaction of Re(CO)(5)Cl with a previously reported mono-RU complex [Ru(bpy)(2)-dpdpz](PF6)(2) in moderate yields. Surprisingly, the reaction of [Re(CO)(3)Cl-dpdpz] or [Re(CO)(3)Cl-dpdpz-Re(CO)(3)Cl] with Ru(tpy)Cl-3 in the presence of AgOTf both afforded an asymmetric bis-Ru complex [Ru(tpy)-dpdpz-RuCl(tpy)](PF6)(2). The solid-state structures of [Re(CO)(3)Cl-dpdpz-Re(CO)(3)Cl] and [Ru(tpy)-dpdpz-RuCl(tpy)](PF6)(2) were determined by single-crystal X-ray analysis. The electrochemical, absorption, and emission properties of these compounds were studied by cyclic voltammetric and spectroscopic analyses. In addition, DFT calculations were carried out to aid in the interpretation of these experimental findings. |
| 语种 | 英语 |
| WOS记录号 | WOS:000300116100052 |
| 出版者 | AMER CHEMICAL SOC |
| 源URL | [http://ir.iccas.ac.cn/handle/121111/49197]  |
| 专题 | 中国科学院化学研究所 |
| 通讯作者 | Zhong, Yu-Wu |
| 作者单位 | 1.Chinese Acad Sci, Inst Chem, CAS Key Lab Photochem, Beijing Natl Lab Mol Sci, Beijing 100190, Peoples R China 2.Cornell Univ, Baker Lab, Dept Chem & Chem Biol, Ithaca, NY 14853 USA |
| 推荐引用方式 GB/T 7714 | Wu, Si-Hai,Abruna, Hector D.,Zhong, Yu-Wu. Rhenium Complexes of 2,3-Di(2-pyridyl)-5,6-diphenylpyrazine: Synthesis, Characterization, and Reactivity[J]. ORGANOMETALLICS,2012,31(3):1161-1167. |
| APA | Wu, Si-Hai,Abruna, Hector D.,&Zhong, Yu-Wu.(2012).Rhenium Complexes of 2,3-Di(2-pyridyl)-5,6-diphenylpyrazine: Synthesis, Characterization, and Reactivity.ORGANOMETALLICS,31(3),1161-1167. |
| MLA | Wu, Si-Hai,et al."Rhenium Complexes of 2,3-Di(2-pyridyl)-5,6-diphenylpyrazine: Synthesis, Characterization, and Reactivity".ORGANOMETALLICS 31.3(2012):1161-1167. |
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来源：化学研究所
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