An oligothiophene dye with triphenylamine as side chains for efficient dye-sensitized solar cells
文献类型:期刊论文
作者 | Shang, Huixia1,2,3; Jiang, Kejian1,2; Zhan, Xiaowei1,2 |
刊名 | ORGANIC ELECTRONICS
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出版日期 | 2012-11-01 |
卷号 | 13期号:11页码:2395-2400 |
关键词 | Dye-sensitized Solar Cell Organic Dye Oligothiophene Triphenylamine |
ISSN号 | 1566-1199 |
DOI | 10.1016/j.orgel.2012.07.021 |
英文摘要 | A novel oligothiophene-cyanoacrylic acid photosensitizer with two triphenylamine side chains (7T-2TPA) is designed and synthesized for dye-sensitized solar cells. 7T-2TPA exhibits broad (250-600 nm) and strong absorption (epsilon = 5.0 x 10(4) L mol(-1) cm(-1) at 496 nm). The optical band gap (E-g) is estimated from the onset absorption edge to be 2.07 eV. The oxidation potential E-ox and reduction potential E-red vs NHE of the dye is 0.93 and -1.14 V. respectively. Dye-sensitized solar cell (DSSC) based on 7T-2TPA exhibits an open-circuit voltage (V-oc) of 724 mV, a short-circuit current density (J(sc)) of 16.28 mA cm(-2), a fill factor (FF) of 0.684 and a power conversion efficiency of 8.06%. The efficiency of 8.06% is similar to that for widely used N719-based cell fabricated and measured under the same conditions. (C) 2012 Elsevier B.V. All rights reserved. |
语种 | 英语 |
WOS记录号 | WOS:000311177700026 |
出版者 | ELSEVIER SCIENCE BV |
源URL | [http://ir.iccas.ac.cn/handle/121111/49237] ![]() |
专题 | 中国科学院化学研究所 |
通讯作者 | Jiang, Kejian |
作者单位 | 1.Chinese Acad Sci, Beijing Natl Lab Mol Sci, Beijing 100190, Peoples R China 2.Chinese Acad Sci, Inst Chem, Beijing 100190, Peoples R China 3.Handan Coll, Dept Chem, Handan 056005, Peoples R China |
推荐引用方式 GB/T 7714 | Shang, Huixia,Jiang, Kejian,Zhan, Xiaowei. An oligothiophene dye with triphenylamine as side chains for efficient dye-sensitized solar cells[J]. ORGANIC ELECTRONICS,2012,13(11):2395-2400. |
APA | Shang, Huixia,Jiang, Kejian,&Zhan, Xiaowei.(2012).An oligothiophene dye with triphenylamine as side chains for efficient dye-sensitized solar cells.ORGANIC ELECTRONICS,13(11),2395-2400. |
MLA | Shang, Huixia,et al."An oligothiophene dye with triphenylamine as side chains for efficient dye-sensitized solar cells".ORGANIC ELECTRONICS 13.11(2012):2395-2400. |
入库方式: OAI收割
来源:化学研究所
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