Self-assembled nanostructures of Ag-6[PV3Mo9O40] with N-donor ligands and their catalytic activity
文献类型：期刊论文
| 作者 | Chen, Bingfeng1,2; Li, Fengbo1; Huang, Zhijun1,2; Lu, Tao1,2; Yuan, Yin1,2; Yu, Jialu3; Yuan, Guoqing1 |
| 刊名 | RSC ADVANCES
 |
| 出版日期 | 2012 |
| 卷号 | 2期号:30页码:11449-11456 |
| ISSN号 | 2046-2069 |
| DOI | 10.1039/c2ra21858e |
| 英文摘要 | Four types of nanostructures were obtained by self-assembly of Ag-6[PV3Mo9O40] with N-donor ligands. Monodentate ligands lead to zero-dimensional nanostructures (nanoparticles). Linear didentate bridging ligands result in linear nanorods. Planar didentate chelating ligands develop two-dimensional nanostructures (nanosheets). Nonplanar didentate chelating ligands produce a transition morphology between nanorods and nanosheets. Kinetically driven (U-total(x) < 0) self-assembly processes lead to structures with less defined shapes. Thermodynamically driven self-assembly (U-total(x) is close to zero) produces ordered nanostructures. It is demonstrated that these nanocomposites are active catalysts for activating molecular oxygen under mild conditions. |
| 语种 | 英语 |
| WOS记录号 | WOS:000312145400040 |
| 出版者 | ROYAL SOC CHEMISTRY |
| 源URL | [http://ir.iccas.ac.cn/handle/121111/49279]  |
| 专题 | 中国科学院化学研究所 |
| 通讯作者 | Chen, Bingfeng |
| 作者单位 | 1.Chinese Acad Sci, Inst Chem, Beijing Natl Lab Mol Sci, New Mat Lab, Beijing 100080, Peoples R China 2.Chinese Acad Sci, Grad Univ, Beijing, Peoples R China 3.Tainjin Univ, Dept Chem Engn, Tianjin 300072, Peoples R China |
| 推荐引用方式 GB/T 7714 | Chen, Bingfeng,Li, Fengbo,Huang, Zhijun,et al. Self-assembled nanostructures of Ag-6[PV3Mo9O40] with N-donor ligands and their catalytic activity[J]. RSC ADVANCES,2012,2(30):11449-11456. |
| APA | Chen, Bingfeng.,Li, Fengbo.,Huang, Zhijun.,Lu, Tao.,Yuan, Yin.,...&Yuan, Guoqing.(2012).Self-assembled nanostructures of Ag-6[PV3Mo9O40] with N-donor ligands and their catalytic activity.RSC ADVANCES,2(30),11449-11456. |
| MLA | Chen, Bingfeng,et al."Self-assembled nanostructures of Ag-6[PV3Mo9O40] with N-donor ligands and their catalytic activity".RSC ADVANCES 2.30(2012):11449-11456. |
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来源：化学研究所
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