Environmental Photochemistry of Iron Complexes and Their Involvement in Environmental Chemical Processes
文献类型：期刊论文
| 作者 | Wang Zhaohui1,2; Song Wenjing2; Ma Wanhong2; Zhao Jincai2 |
| 刊名 | PROGRESS IN CHEMISTRY
 |
| 出版日期 | 2012-03-24 |
| 卷号 | 24期号:2-3页码:423-432 |
| 关键词 | Environmental Photochemistry Iron Reactive Oxygen Species Organic Complexes Ligand-to-metal Charge Transfer(Lmct) |
| ISSN号 | 1005-281X |
| 英文摘要 | Iron is one of the most abundant metals in the continental crust, while most of dissolved iron is complexes with organic ligands. The irradiated iron complexes in the environment undergo direct photolysis and secondary (photo) chemical reactions, generating Fe(II), organic radicals and some reactive oxygen species (ROS). Environmental photochemistry of iron complexes can greatly affect ROS dynamics, organics degradation and redox cyclin of other elements. Therefore, it is becoming a hot topic in the international field of environmental sciences research. This review firstly summarizes three types of iron complexes including inorganic Fe complexes, simple organic Fe complexes and macrocyclic organic Fe complexes, and photoreduction mechanisms of iron complexes. Secondly, the potential oxidants of Fe(II) in acidic aquatic environment are introduced. The oxidation kinectics, possible reaction mechanism and influencing factors (such as dissolved oxygen concentration, pH, ionic strength, temperature and natural organic matters concentrations) of (photo) chemical oxidation of Fe(II) are elucidated. This review also highlights recent findings in the study of environmental processes involving iron photochemistry. Finally, the future prospects in this field are discussed based on the current status. |
| 语种 | 英语 |
| WOS记录号 | WOS:000304130800024 |
| 出版者 | CHINESE ACAD SCIENCES |
| 源URL | [http://ir.iccas.ac.cn/handle/121111/49309]  |
| 专题 | 中国科学院化学研究所 |
| 通讯作者 | Wang Zhaohui |
| 作者单位 | 1.Donghua Univ, Coll Environm Sci & Engn, Shanghai 201620, Peoples R China 2.Chinese Acad Sci, Inst Chem, Beijing Natl Lab Mol Sci, Beijing 100190, Peoples R China |
| 推荐引用方式 GB/T 7714 | Wang Zhaohui,Song Wenjing,Ma Wanhong,et al. Environmental Photochemistry of Iron Complexes and Their Involvement in Environmental Chemical Processes[J]. PROGRESS IN CHEMISTRY,2012,24(2-3):423-432. |
| APA | Wang Zhaohui,Song Wenjing,Ma Wanhong,&Zhao Jincai.(2012).Environmental Photochemistry of Iron Complexes and Their Involvement in Environmental Chemical Processes.PROGRESS IN CHEMISTRY,24(2-3),423-432. |
| MLA | Wang Zhaohui,et al."Environmental Photochemistry of Iron Complexes and Their Involvement in Environmental Chemical Processes".PROGRESS IN CHEMISTRY 24.2-3(2012):423-432. |
入库方式： OAI收割
来源：化学研究所
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