Syntheses and properties of a series of chromium vanadates ACrV(2)O(7) (A=Na, K, Rb, Cs) with layered structure
文献类型：期刊论文
| 作者 | Wang, Yonggang1; Liang, Jie1; Wen, Ting2; Li, Kuo1; Wang, Yingxia1; Li, Guobao1; Liao, Fuhui1; Lin, Jianhua1 |
| 刊名 | JOURNAL OF SOLID STATE CHEMISTRY
 |
| 出版日期 | 2012-08-01 |
| 卷号 | 192页码:1-6 |
| 关键词 | Chromium Vanadate Layered Structure Powder Diffraction Ion-exchange Alkali Metal |
| ISSN号 | 0022-4596 |
| DOI | 10.1016/j.jssc.2012.03.025 |
| 英文摘要 | A series of layered compounds ACrV(2)O(7) (A=Na, K, Rb, Cs) were investigated by means of powder X-ray diffraction technique, thermal analysis and IR spectroscopy. As a new member in this family, the structure of CsCrV2O7 is confirmed by Rietveld refinement applying powder X-ray diffraction data. Isostructural NaCrV2O7 was obtained by ion-exchange reaction of KCrV2O7 in NaNO3 melt under 350 degrees C and was testified to be a metastable phase. These compounds crystallize in a monoclinic structure in the space group P2/c, and consist of planar CrV2O7- slabs interleaved by alkali-metal cations. ACrV(2)O(7) (A=K, Rb, Cs) present decreasing melting points and characteristic vibration of V=O bond in IR spectra. Magnetic measurements reveal weak antiferromagnetic interactions between Cr3+ cations in the isolated chains. (C) 2012 Elsevier Inc. All rights reserved. |
| 语种 | 英语 |
| WOS记录号 | WOS:000307028300001 |
| 出版者 | ACADEMIC PRESS INC ELSEVIER SCIENCE |
| 源URL | [http://ir.iccas.ac.cn/handle/121111/49335]  |
| 专题 | 中国科学院化学研究所 |
| 通讯作者 | Wang, Yingxia |
| 作者单位 | 1.Peking Univ, Beijing Natl Lab Mol Sci, State Key Lab Rare Earth Mat Chem & Applicat, Coll Chem & Mol Engn, Beijing 100871, Peoples R China 2.Huanghe Sci & Technol Coll, Inst Nanostruct Funct Mat, Zhengzhou 450006, Henan, Peoples R China |
| 推荐引用方式 GB/T 7714 | Wang, Yonggang,Liang, Jie,Wen, Ting,et al. Syntheses and properties of a series of chromium vanadates ACrV(2)O(7) (A=Na, K, Rb, Cs) with layered structure[J]. JOURNAL OF SOLID STATE CHEMISTRY,2012,192:1-6. |
| APA | Wang, Yonggang.,Liang, Jie.,Wen, Ting.,Li, Kuo.,Wang, Yingxia.,...&Lin, Jianhua.(2012).Syntheses and properties of a series of chromium vanadates ACrV(2)O(7) (A=Na, K, Rb, Cs) with layered structure.JOURNAL OF SOLID STATE CHEMISTRY,192,1-6. |
| MLA | Wang, Yonggang,et al."Syntheses and properties of a series of chromium vanadates ACrV(2)O(7) (A=Na, K, Rb, Cs) with layered structure".JOURNAL OF SOLID STATE CHEMISTRY 192(2012):1-6. |
入库方式： OAI收割
来源：化学研究所
浏览0
下载0
收藏0
其他版本
除非特别说明，本系统中所有内容都受版权保护，并保留所有权利。