Double Asynchronous Orthogonal Sample Design Scheme for Probing Intermolecular Interactions
文献类型：期刊论文
| 作者 | Chen, Jing2; Bi, Quan2,3; Liu, Shaoxuan2; Li, Xiaopei2,4; Liu, Yuhai5; Zhai, Yanjun3; Zhao, Ying5; Yang, Limin1; Xu, Yizhuang2; Noda, Isao6 |
| 刊名 | JOURNAL OF PHYSICAL CHEMISTRY A
 |
| 出版日期 | 2012-11-15 |
| 卷号 | 116期号:45页码:10904-10916 |
| ISSN号 | 1089-5639 |
| DOI | 10.1021/jp300918g |
| 英文摘要 | This paper introduces a new approach called double asynchronous orthogonal sample design (DAOSD) to probe intermolecular interactions. A specifically designed concentration series is selected according to the mathematical analysis to generate useful 2D correlated spectra. As a result, the interfering portions are completely removed and a pair of complementary sub-2D asynchronous spectra can be obtained. A computer simulation is applied on a model system with two solutes to study the spectral behavior of cross peaks in 2D asynchronous spectra generated by using the DAOSD approach. Variations on different spectral parameters, such as peak position, bandwidth, and absorptivity, caused by intermolecular interactions can be estimated by the characteristic spectral patterns of cross peaks in the pair of complementary sub-2D asynchronous spectra. Intermolecular interactions between benzene and iodine in CCl4 solutions were investigated using the DAOSD approach to prove the applicability of the DAOSD method in real chemical system. |
| 语种 | 英语 |
| WOS记录号 | WOS:000311192400005 |
| 出版者 | AMER CHEMICAL SOC |
| 源URL | [http://ir.iccas.ac.cn/handle/121111/49391]  |
| 专题 | 中国科学院化学研究所 |
| 通讯作者 | Yang, Limin |
| 作者单位 | 1.Peking Univ, State Key Lab Nucl Phys & Technol, Inst Heavy Ion Phys, Sch Phys, Beijing 100871, Peoples R China 2.Peking Univ, Beijing Natl Lab Mol Sci, State Key Lab Rare Earth Mat Chem & Applicat, Coll Chem & Mol Engn, Beijing 100871, Peoples R China 3.Liaoning Univ Tradit Chinese Med, Coll Pharm, Shenyang 11660, Peoples R China 4.Chinese Acad Sci, Inst Proc Engn, Beijing 100190, Peoples R China 5.Chinese Acad Sci, Inst Chem, Beijing 100190, Peoples R China 6.Univ Delaware, Dept Mat Sci & Engn, Newark, DE 19716 USA |
| 推荐引用方式 GB/T 7714 | Chen, Jing,Bi, Quan,Liu, Shaoxuan,et al. Double Asynchronous Orthogonal Sample Design Scheme for Probing Intermolecular Interactions[J]. JOURNAL OF PHYSICAL CHEMISTRY A,2012,116(45):10904-10916. |
| APA | Chen, Jing.,Bi, Quan.,Liu, Shaoxuan.,Li, Xiaopei.,Liu, Yuhai.,...&Wu, Jinguang.(2012).Double Asynchronous Orthogonal Sample Design Scheme for Probing Intermolecular Interactions.JOURNAL OF PHYSICAL CHEMISTRY A,116(45),10904-10916. |
| MLA | Chen, Jing,et al."Double Asynchronous Orthogonal Sample Design Scheme for Probing Intermolecular Interactions".JOURNAL OF PHYSICAL CHEMISTRY A 116.45(2012):10904-10916. |
入库方式： OAI收割
来源：化学研究所
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