2-(1-(Arylimino)ethyl)-8-arylimino-5,6,7-trihydroquinoline Iron(II) Chloride Complexes: Synthesis, Characterization, and Ethylene Polymerization Behavior
文献类型：期刊论文
| 作者 | Zhang, Wenjuan1,2; Chai, Wenbin1,2,3; Sun, Wen-Hua1,2 ; Hu, Xinquan3; Redshaw, Carl4; Hao, Xiang1,2
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| 刊名 | ORGANOMETALLICS
 |
| 出版日期 | 2012-07-23 |
| 卷号 | 31期号:14页码:5039-5048 |
| ISSN号 | 0276-7333 |
| DOI | 10.1021/om300388m |
| 英文摘要 | The series of 2-(1-(arylimino)ethyl)-8-arylimino-5,6,7-trihydroquinolines was synthesized and fully characterized, for which data indicated two isomer forms of each due to the migration of a double bond. The corresponding iron dichloride complexes were prepared and were found to adopt distorted bipyramidal coordination geometry at iron by single-crystal X-ray diffraction studies. Upon treatment with either MAO or MMAO, all iron complex precatalysts exhibited high activities (up to 2.4 x 10(7) gPE.mol(-1)(Fe).h(-1)) toward ethylene polymerization. The influence of the nature of the ligands and reaction parameters upon the catalytic activities and properties of the polyethylene obtained has been studied. |
| 语种 | 英语 |
| WOS记录号 | WOS:000306613600015 |
| 出版者 | AMER CHEMICAL SOC |
| 源URL | [http://ir.iccas.ac.cn/handle/121111/49409]  |
| 专题 | 中国科学院化学研究所 |
| 通讯作者 | Sun, Wen-Hua |
| 作者单位 | 1.Chinese Acad Sci, Inst Chem, Key Lab Engn Plast, Beijing 100190, Peoples R China 2.Chinese Acad Sci, Inst Chem, Beijing Natl Lab Mol Sci, Beijing 100190, Peoples R China 3.Zhejiang Univ Technol, Coll Chem Engn & Mat Sci, Hangzhou 310014, Zhejiang, Peoples R China 4.Univ E Anglia, Sch Chem, Norwich NR4 7TJ, Norfolk, England |
| 推荐引用方式 GB/T 7714 | Zhang, Wenjuan,Chai, Wenbin,Sun, Wen-Hua,et al. 2-(1-(Arylimino)ethyl)-8-arylimino-5,6,7-trihydroquinoline Iron(II) Chloride Complexes: Synthesis, Characterization, and Ethylene Polymerization Behavior[J]. ORGANOMETALLICS,2012,31(14):5039-5048. |
| APA | Zhang, Wenjuan,Chai, Wenbin,Sun, Wen-Hua,Hu, Xinquan,Redshaw, Carl,&Hao, Xiang.(2012).2-(1-(Arylimino)ethyl)-8-arylimino-5,6,7-trihydroquinoline Iron(II) Chloride Complexes: Synthesis, Characterization, and Ethylene Polymerization Behavior.ORGANOMETALLICS,31(14),5039-5048. |
| MLA | Zhang, Wenjuan,et al."2-(1-(Arylimino)ethyl)-8-arylimino-5,6,7-trihydroquinoline Iron(II) Chloride Complexes: Synthesis, Characterization, and Ethylene Polymerization Behavior".ORGANOMETALLICS 31.14(2012):5039-5048. |
入库方式： OAI收割
来源：化学研究所
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