Alkene Synthesis Through Transition Metal-Catalyzed Cross-Coupling of N-Tosylhydrazones
文献类型：期刊论文
| 作者 | Zhang, Yan; Wang, Jianbo; Wang, J |
| 刊名 | STEREOSELECTIVE ALKENE SYNTHESIS
 |
| 出版日期 | 2012 |
| 卷号 | 327页码:239-269 |
| 关键词 | Alkene Synthesis Cross-coupling Metal Carbene N-tosylhydrazones |
| ISSN号 | 0340-1022 |
| DOI | 10.1007/128_2012_322 |
| 英文摘要 | In this chapter, alkene synthesis based on the reaction of N-tosylhydrazones is described. The reactivity of tosylhydrazones is determined by either the acidity of alpha-proton and hydrazone proton or the electropositivity of the carbon of C-N bond. This leads to diverse reactivities and a series of N-tosylhydrazone-based olefination methodologies. Both non-catalytic and transition metal-catalyzed olefinations from N-tosylhydrazones are introduced in this chapter. Most of the transition metal-catalyzed reactions proceed via metal carbene transformations. The synthesis of alkenes through Pd-catalyzed cross-coupling reactions of N-tosylhydrazones is particularly attractive and will be discussed in detail. |
| 语种 | 英语 |
| WOS记录号 | WOS:000321634900009 |
| 出版者 | SPRINGER-VERLAG BERLIN |
| 源URL | [http://ir.iccas.ac.cn/handle/121111/49449]  |
| 专题 | 中国科学院化学研究所 |
| 通讯作者 | Wang, Jianbo |
| 作者单位 | Peking Univ, BNLMS, Key Lab Bioorgan Chem & Mol Engn, Minist Educ,Coll Chem, Beijing 100871, Peoples R China |
| 推荐引用方式 GB/T 7714 | Zhang, Yan,Wang, Jianbo,Wang, J. Alkene Synthesis Through Transition Metal-Catalyzed Cross-Coupling of N-Tosylhydrazones[J]. STEREOSELECTIVE ALKENE SYNTHESIS,2012,327:239-269. |
| APA | Zhang, Yan,Wang, Jianbo,&Wang, J.(2012).Alkene Synthesis Through Transition Metal-Catalyzed Cross-Coupling of N-Tosylhydrazones.STEREOSELECTIVE ALKENE SYNTHESIS,327,239-269. |
| MLA | Zhang, Yan,et al."Alkene Synthesis Through Transition Metal-Catalyzed Cross-Coupling of N-Tosylhydrazones".STEREOSELECTIVE ALKENE SYNTHESIS 327(2012):239-269. |
入库方式： OAI收割
来源：化学研究所
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