High-conversion synthesis of poly(3,4-ethylenedioxythiophene) by chemical oxidative polymerization
文献类型：期刊论文
| 作者 | Jiang, Chengqun1,2; Chen, Guangming1; Wang, Xin2 |
| 刊名 | SYNTHETIC METALS
 |
| 出版日期 | 2012-12-01 |
| 卷号 | 162期号:21-22页码:1968-1971 |
| 关键词 | High Conversion Synthesis Oxidative Chemical Polymerization Poly(3 4-ethylenedioxythiophene) |
| ISSN号 | 0379-6779 |
| DOI | 10.1016/j.synthmet.2012.09.008 |
| 英文摘要 | High-conversion synthesis of poly(3,4-ethylenedioxythiophene) (PEDOT) by chemical oxidative polymerization was studied. Hydrolysis of oxidative agent, and effects of polymerization temperature and time were taken into account. Unlike iron chloride, the oxidative agent of iron sulfate can be effectively used at high temperature, due to the absence of obvious hydrolysis. In addition, high polymerization temperature and long reaction time led to dramatically increase of conversion. Moreover, the structure, morphology and electrical conductivity of the prepared PEDOT with high-conversion had not been changed obviously, when compared with the common low-conversed product obtained at low temperature with short reaction time. (C) 2012 Elsevier B.V. All rights reserved. |
| 语种 | 英语 |
| WOS记录号 | WOS:000311917900030 |
| 出版者 | ELSEVIER SCIENCE SA |
| 源URL | [http://ir.iccas.ac.cn/handle/121111/49463]  |
| 专题 | 中国科学院化学研究所 |
| 通讯作者 | Chen, Guangming |
| 作者单位 | 1.Chinese Acad Sci, Beijing Natl Lab Mol Sci, Inst Chem, Beijing 100190, Peoples R China 2.Qingdao Univ Sci & Technol, Key Lab Rubber Plast, Minist Educ, Qingdao 266042, Peoples R China |
| 推荐引用方式 GB/T 7714 | Jiang, Chengqun,Chen, Guangming,Wang, Xin. High-conversion synthesis of poly(3,4-ethylenedioxythiophene) by chemical oxidative polymerization[J]. SYNTHETIC METALS,2012,162(21-22):1968-1971. |
| APA | Jiang, Chengqun,Chen, Guangming,&Wang, Xin.(2012).High-conversion synthesis of poly(3,4-ethylenedioxythiophene) by chemical oxidative polymerization.SYNTHETIC METALS,162(21-22),1968-1971. |
| MLA | Jiang, Chengqun,et al."High-conversion synthesis of poly(3,4-ethylenedioxythiophene) by chemical oxidative polymerization".SYNTHETIC METALS 162.21-22(2012):1968-1971. |
入库方式： OAI收割
来源：化学研究所
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