Electronic Coupling between Two Amine Redox Sites through the 5,5 '-Positions of Metal-Chelating 2,2 '-Bipyridines
文献类型：期刊论文
| 作者 | Nie, Hai-Jing1; Chen, Xialing2; Yao, Chang-Jiang1; Zhong, Yu-Wu1,3; Hutchison, Geoffrey R.2; Yao, Jiannian1 |
| 刊名 | CHEMISTRY-A EUROPEAN JOURNAL
 |
| 出版日期 | 2012-11-01 |
| 卷号 | 18期号:45页码:14497-14509 |
| 关键词 | Chelates Density Functional Calculations Donor-acceptor Systems Mixed-valent Compounds n Ligands |
| ISSN号 | 0947-6539 |
| DOI | 10.1002/chem.201201813 |
| 英文摘要 | Electron delocalization of new mixed-valent (MV) systems with the aid of lateral metal chelation is reported. 2,2'-Bipyridine (bpy) derivatives with one or two appended di-p-anisylamino groups on the 5,5'-positions and a coordinated [Ru(bpy)2] (bpy=2,2'-bipyridine), [Re(CO)3Cl], or [Ir(ppy)2] (ppy=2-phenylpyridine) component were prepared. The single-crystal molecular structure of the bis-amine ligand without metal chelation is presented. The electronic properties of these complexes were studied and compared by electrochemical and spectroscopic techniques and DFT/TDDFT calculations. Compounds with two di-p-anisylamino groups were oxidized by a chemical or electrochemical method and monitored by near-infrared (NIR) absorption spectral changes. MarcusHush analysis of the resulting intervalence charge-transfer transitions indicated that electron coupling of these mixed-valent systems is enhanced by metal chelation and that the iridium complex has the largest coupling. TDDFT calculations were employed to interpret the NIR transitions of these MV systems. |
| 语种 | 英语 |
| WOS记录号 | WOS:000310474800035 |
| 出版者 | WILEY-V C H VERLAG GMBH |
| 源URL | [http://ir.iccas.ac.cn/handle/121111/49553]  |
| 专题 | 中国科学院化学研究所 |
| 通讯作者 | Zhong, Yu-Wu |
| 作者单位 | 1.Chinese Acad Sci, Beijing Natl Lab Mol Sci, CAS Key Lab Photochem, Inst Chem, Beijing 100190, Peoples R China 2.Univ Pittsburgh, Dept Chem, Pittsburgh, PA 15260 USA 3.Nanjing Univ, State Key Lab Coordinat Chem, Nanjing 210093, Jiangsu, Peoples R China |
| 推荐引用方式 GB/T 7714 | Nie, Hai-Jing,Chen, Xialing,Yao, Chang-Jiang,et al. Electronic Coupling between Two Amine Redox Sites through the 5,5 '-Positions of Metal-Chelating 2,2 '-Bipyridines[J]. CHEMISTRY-A EUROPEAN JOURNAL,2012,18(45):14497-14509. |
| APA | Nie, Hai-Jing,Chen, Xialing,Yao, Chang-Jiang,Zhong, Yu-Wu,Hutchison, Geoffrey R.,&Yao, Jiannian.(2012).Electronic Coupling between Two Amine Redox Sites through the 5,5 '-Positions of Metal-Chelating 2,2 '-Bipyridines.CHEMISTRY-A EUROPEAN JOURNAL,18(45),14497-14509. |
| MLA | Nie, Hai-Jing,et al."Electronic Coupling between Two Amine Redox Sites through the 5,5 '-Positions of Metal-Chelating 2,2 '-Bipyridines".CHEMISTRY-A EUROPEAN JOURNAL 18.45(2012):14497-14509. |
入库方式： OAI收割
来源：化学研究所
浏览0
下载0
收藏0
其他版本
除非特别说明，本系统中所有内容都受版权保护，并保留所有权利。