Syntheses and structures of two open-framework zinc phosphites with extra-large 24-ring channels
文献类型：期刊论文
| 作者 | Wang, Pei1; Wang, Guo-Ming1; Li, Jin-Hua1; Wang, Zong-Hua1; Wang, Ying-Xia2; Lin, Jian-Hua2 |
| 刊名 | SOLID STATE SCIENCES
 |
| 出版日期 | 2012-08-01 |
| 卷号 | 14期号:8页码:1030-1035 |
| ISSN号 | 1293-2558 |
| 关键词 | Zinc Phosphite 24-ring Channel Crystal Structure Open-framework Hydrothermal Synthesis |
| DOI | 10.1016/j.solidstatesciences.2012.05.007 |
| 英文摘要 | Two new three-dimensional open-framework zinc phosphites, [HCHA](2)[Zn-3(HPO3)(4)] (1) and [HCHPA](2)[Zn-3(HPO3)(4)] (2), have been synthesized under hydrothermal conditions, where CHA = cyclohexylamine and CHPA = cycloheptylamine. Both compounds are isostructural and exhibit a similar three-dimensional 3, 4-connected framework constructed by strictly alternating ZnO4 tetrahedra and HPO32- pseudopyramids. The occurrence of extra-large tubular channels constructed by the concatenation of 24- and 30-ring windows along the [001] direction in the two structures is very unusual in known extra-large micropore materials. Crystal data: 1, rhombohedral, R-3, a = 32.9618(5) angstrom, c = 13.2818(3) angstrom, V = 12497.1(4) angstrom(3), Z = 18, R-1 = 0.0445, wR(2) = 0.1068; 2, rhombohedral, R-3, a = 33.2184(4) angstrom, c = 13.1697(6) angstrom, V = 12585.3(6) angstrom(3), Z = 18, R-1 = 0.0401, wR(2) = 0.0974. (C) 2012 Elsevier Masson SAS. All rights reserved. |
| 语种 | 英语 |
| 出版者 | ELSEVIER SCIENCE BV |
| WOS记录号 | WOS:000308769000006 |
| 源URL | [http://ir.iccas.ac.cn/handle/121111/49605]  |
| 专题 | 中国科学院化学研究所 |
| 通讯作者 | Wang, Guo-Ming |
| 作者单位 | 1.Qingdao Univ, Teachers Coll, Coll Chem Chem Engn & Environm, Qingda 266071, Shandong, Peoples R China 2.Peking Univ, Beijing Natl Lab Mol Sci, Coll Chem & Mol Engn, Beijing 100871, Peoples R China |
| 推荐引用方式 GB/T 7714 | Wang, Pei,Wang, Guo-Ming,Li, Jin-Hua,et al. Syntheses and structures of two open-framework zinc phosphites with extra-large 24-ring channels[J]. SOLID STATE SCIENCES,2012,14(8):1030-1035. |
| APA | Wang, Pei,Wang, Guo-Ming,Li, Jin-Hua,Wang, Zong-Hua,Wang, Ying-Xia,&Lin, Jian-Hua.(2012).Syntheses and structures of two open-framework zinc phosphites with extra-large 24-ring channels.SOLID STATE SCIENCES,14(8),1030-1035. |
| MLA | Wang, Pei,et al."Syntheses and structures of two open-framework zinc phosphites with extra-large 24-ring channels".SOLID STATE SCIENCES 14.8(2012):1030-1035. |
入库方式： OAI收割
来源：化学研究所
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