Synthesis and structural characterization of a novel two-dimensional 3d-4f heterometallic coordination framework based on pentanuclear lanthanide cluster
文献类型：期刊论文
| 作者 | Wang, Guo-Ming1; Li, Jin-Hua1; Li, Zeng-Xin1; Wang, Pei1; Wang, Ying-Xia2; Lin, Jian-Hua2 |
| 刊名 | SOLID STATE SCIENCES
 |
| 出版日期 | 2012-04-01 |
| 卷号 | 14期号:4页码:445-450 |
| 关键词 | Hydrothermal Synthesis Coordination Polymer Crystal Structure Isonicotinic Acid Tm-cu Heterometallic Complex 1 2-benzenedicarboxylic Acid |
| ISSN号 | 1293-2558 |
| DOI | 10.1016/j.solidstatesciences.2012.01.018 |
| 英文摘要 | A novel 3d-4f heterometallic coordination polymer, {[Tm-5(mu(3)-OH)(2)(BDC)(6)(IN)(2)Cu(H2O)(2)]center dot(H2O)(3)}(n) (1) [BDC = benzene-1,2-dicarboxylate, IN = isonicotinate], has been hydrothermally synthesized and structurally characterized by single crystal X-ray diffraction, FTIR, elemental analysis, powder X-ray diffraction and thermogravimetric analysis. The compound crystallizes in monoclinic system, space group P2(1)/c (No. 14), a = 13.7302(5) angstrom, b = 23.5428(3) angstrom, c = 21.5789(2) angstrom, beta = 91.491(3)degrees, V = 6973.0(3) angstrom(3), and Z = 4. The structure exhibits unusual two-dimensional Tm-carboxylate layer, which is constructed from the expansion of novel pentanuclear {Tm-5} clusters. More interestingly, the heterometallic Cu(I) ions were successfully planted into such Ln-carboxylate layer by the bifunctional IN bridging ligands, resulting in the formation of an unprecedented 2D heterometallic lanthanide-transition-metal framework. (C) 2012 Elsevier Masson SAS. All rights reserved. |
| 语种 | 英语 |
| WOS记录号 | WOS:000303087500007 |
| 出版者 | ELSEVIER SCIENCE BV |
| 源URL | [http://ir.iccas.ac.cn/handle/121111/49625]  |
| 专题 | 中国科学院化学研究所 |
| 通讯作者 | Wang, Guo-Ming |
| 作者单位 | 1.Qingdao Univ, Teachers Coll, Coll Chem Chem Engn & Environm, Qingdao 266071, Shandong, Peoples R China 2.Peking Univ, Beijing Natl Lab Mol Sci, Coll Chem & Mol Engn, Beijing 100871, Peoples R China |
| 推荐引用方式 GB/T 7714 | Wang, Guo-Ming,Li, Jin-Hua,Li, Zeng-Xin,et al. Synthesis and structural characterization of a novel two-dimensional 3d-4f heterometallic coordination framework based on pentanuclear lanthanide cluster[J]. SOLID STATE SCIENCES,2012,14(4):445-450. |
| APA | Wang, Guo-Ming,Li, Jin-Hua,Li, Zeng-Xin,Wang, Pei,Wang, Ying-Xia,&Lin, Jian-Hua.(2012).Synthesis and structural characterization of a novel two-dimensional 3d-4f heterometallic coordination framework based on pentanuclear lanthanide cluster.SOLID STATE SCIENCES,14(4),445-450. |
| MLA | Wang, Guo-Ming,et al."Synthesis and structural characterization of a novel two-dimensional 3d-4f heterometallic coordination framework based on pentanuclear lanthanide cluster".SOLID STATE SCIENCES 14.4(2012):445-450. |
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来源：化学研究所
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