Graphene Oxide as a Monoatomic Blocking Layer
文献类型:期刊论文
作者 | Petersen, Soren1,2; Glyvradal, Magni1,3; Boggild, Peter4; Hu, Wenping5; Feidenhans'l, Robert1,3; Laursen, Bo W.1,2 |
刊名 | ACS NANO
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出版日期 | 2012-09-01 |
卷号 | 6期号:9页码:8022-8029 |
关键词 | Graphene Oxide Molecular Electronics Vertical Devices Barrier Layer Molecular Interfacing X-ray Reflectivity |
ISSN号 | 1936-0851 |
DOI | 10.1021/nn302628q |
英文摘要 | Monolayer graphene oxide (mGO) is shown to effectively protect molecular thin films from reorganization and function as an atomically thin barrier for vapor-deposited Ti/Al metal top electrodes. Fragile organic Langmuir-Blodgett (LB) films of C-22 fatty acid cadmium salts (cadmium(II) behenate) were covered by a compressed mosaic LB film of mGO flakes. These hybrid LB films were examined with atomic force microscopy (AFM) and X-ray reflectivity, both with and without the metal top electrodes. While the AFM enabled surface and morphology analysis, the X-ray reflectivity allowed for a detailed structural depth profiling of the organic film and mGO layer below the metal top layers. The structure of the mGO-protected LB films was found to be perfectly preserved; in contrast, it has previously been shown that metal deposition completely destroys the first two LB layers of unprotected films. This study provides dear evidence of the efficient protection offered by a single atomic layer of GO. |
语种 | 英语 |
WOS记录号 | WOS:000309040600053 |
出版者 | AMER CHEMICAL SOC |
源URL | [http://ir.iccas.ac.cn/handle/121111/49631] ![]() |
专题 | 中国科学院化学研究所 |
通讯作者 | Laursen, Bo W. |
作者单位 | 1.Univ Copenhagen, Nanosci Ctr, Copenhagen, Denmark 2.Univ Copenhagen, Dept Chem, DK-2100 Copenhagen, Denmark 3.Univ Copenhagen, Niels Bohr Inst, DK-2100 Copenhagen, Denmark 4.Tech Univ Denmark, DTU Nanotech, DK-2800 Lyngby, Denmark 5.Chinese Acad Sci, Inst Chem, Beijing 100080, Peoples R China |
推荐引用方式 GB/T 7714 | Petersen, Soren,Glyvradal, Magni,Boggild, Peter,et al. Graphene Oxide as a Monoatomic Blocking Layer[J]. ACS NANO,2012,6(9):8022-8029. |
APA | Petersen, Soren,Glyvradal, Magni,Boggild, Peter,Hu, Wenping,Feidenhans'l, Robert,&Laursen, Bo W..(2012).Graphene Oxide as a Monoatomic Blocking Layer.ACS NANO,6(9),8022-8029. |
MLA | Petersen, Soren,et al."Graphene Oxide as a Monoatomic Blocking Layer".ACS NANO 6.9(2012):8022-8029. |
入库方式: OAI收割
来源:化学研究所
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