Synthesis of Chiral Olefin Ligands and their Application in Asymmetric Catalysis
文献类型：期刊论文
| 作者 | Feng, Xiangqing; Du, Haifeng |
| 刊名 | ASIAN JOURNAL OF ORGANIC CHEMISTRY
 |
| 出版日期 | 2012-11-01 |
| 卷号 | 1期号:3页码:204-213 |
| ISSN号 | 2193-5807 |
| 关键词 | Alkenes Asymmetric Catalysis Dienes Phosphorus Sulfur |
| DOI | 10.1002/ajoc.201200069 |
| 英文摘要 | Chiral olefins have recently emerged as among the most promising ligands for asymmetric catalysis. In the past nearly ten years, significant advances have been made in developing ligands, including diene and heteroatom/olefin hybrid ligands, and exploring their applications in challenging metal-catalyzed asymmetric reactions. Especially in some cases, chiral olefin ligands have an obvious advantage over some conventional chiral ligands in terms of activity and selectivity. Besides the most often studied rigidly bicyclic dienes, readily accessible chiral-chain dienes with flexible frameworks and two terminal olefins as coordinating groups have also proven to be effective for achieving high levels of enantioselectivity in transition-metal-catalyzed asymmetric reactions. Moreover, the terminal olefins can be combined with phosphorus atoms on suitable chiral skeletons for the development of novel phosphorus/olefin (P/olefin) hybrid ligands, which have high activity and selectivity in Pd-catalyzed asymmetric transformations. Significantly, sulfur/olefin (S/olefin) hybrid ligands have been successfully explored and applied in a range of Rh-catalyzed asymmetric transformations. This Focus Review will mainly discuss the synthesis of recently developed chiral-chain diene ligands, phosphorus/terminal-olefin hybrid ligands, and sulfur/olefin hybrid ligands, and their application in asymmetric catalysis. |
| 语种 | 英语 |
| 出版者 | WILEY-V C H VERLAG GMBH |
| WOS记录号 | WOS:000325946900001 |
| 源URL | [http://ir.iccas.ac.cn/handle/121111/49701]  |
| 专题 | 中国科学院化学研究所 |
| 通讯作者 | Feng, Xiangqing |
| 作者单位 | Chinese Acad Sci, Beijing Natl Lab Mol Sci, CAS Key Lab Mol Recognit & Funct, Inst Chem, Beijing 100190, Peoples R China |
| 推荐引用方式 GB/T 7714 | Feng, Xiangqing,Du, Haifeng. Synthesis of Chiral Olefin Ligands and their Application in Asymmetric Catalysis[J]. ASIAN JOURNAL OF ORGANIC CHEMISTRY,2012,1(3):204-213. |
| APA | Feng, Xiangqing,&Du, Haifeng.(2012).Synthesis of Chiral Olefin Ligands and their Application in Asymmetric Catalysis.ASIAN JOURNAL OF ORGANIC CHEMISTRY,1(3),204-213. |
| MLA | Feng, Xiangqing,et al."Synthesis of Chiral Olefin Ligands and their Application in Asymmetric Catalysis".ASIAN JOURNAL OF ORGANIC CHEMISTRY 1.3(2012):204-213. |
入库方式： OAI收割
来源：化学研究所
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