Synthesis and Third-Order Nonlinear Optical Properties of Copper and Nickel Coordination Complexes of Azo Dyes
文献类型：期刊论文
| 作者 | Zhang, Yongfang1; Gan, Quan2; Wang, Shuangqing2; Yang, Guoqiang2 |
| 刊名 | JOURNAL OF INORGANIC AND ORGANOMETALLIC POLYMERS AND MATERIALS
 |
| 出版日期 | 2012 |
| 卷号 | 22期号:1页码:48-53 |
| 关键词 | Azo Metallic Chelate Nonlinear Optics Z-scan Self-defocusing |
| ISSN号 | 1574-1443 |
| DOI | 10.1007/s10904-011-9621-4 |
| 英文摘要 | An azo dye, 2-(4,5-dicyano-1-H-imidazolyazo)-5-N, N-diethylaminophenol, and the corresponding divalent copper and nickel mononuclear coordination complexes were synthesized. The molecular third-order nonlinear optical characteristics of these azo transition metallic chelates were investigated in N, N'-dimethylformamide solution using a standard Z-scan technique with a 7-ns laser pulses at 1,064 nm. The results of n(2) (the nonlinear refraction index) and gamma (the hyperpolarizability) values of the two complexes indicated that metal chelating lead to considerable enhancement in third-order optical nonlinearities, which revealed that such coordination complexes exhibit strong nonlinear optical absorption effects and self-defocusing performance. These materials are promising candidates as large third-order nonlinear optical materials. |
| 语种 | 英语 |
| WOS记录号 | WOS:000301518100010 |
| 出版者 | SPRINGER |
| 源URL | [http://ir.iccas.ac.cn/handle/121111/49747]  |
| 专题 | 中国科学院化学研究所 |
| 通讯作者 | Zhang, Yongfang |
| 作者单位 | 1.Univ Jinan UJN, Sch Resources & Environm, Jinan 250022, Peoples R China 2.Chinese Acad Sci, Inst Chem, Beijing Natl Lab Mol Sci, Key Lab Photochem, Beijing 100080, Peoples R China |
| 推荐引用方式 GB/T 7714 | Zhang, Yongfang,Gan, Quan,Wang, Shuangqing,et al. Synthesis and Third-Order Nonlinear Optical Properties of Copper and Nickel Coordination Complexes of Azo Dyes[J]. JOURNAL OF INORGANIC AND ORGANOMETALLIC POLYMERS AND MATERIALS,2012,22(1):48-53. |
| APA | Zhang, Yongfang,Gan, Quan,Wang, Shuangqing,&Yang, Guoqiang.(2012).Synthesis and Third-Order Nonlinear Optical Properties of Copper and Nickel Coordination Complexes of Azo Dyes.JOURNAL OF INORGANIC AND ORGANOMETALLIC POLYMERS AND MATERIALS,22(1),48-53. |
| MLA | Zhang, Yongfang,et al."Synthesis and Third-Order Nonlinear Optical Properties of Copper and Nickel Coordination Complexes of Azo Dyes".JOURNAL OF INORGANIC AND ORGANOMETALLIC POLYMERS AND MATERIALS 22.1(2012):48-53. |
入库方式： OAI收割
来源：化学研究所
浏览0
下载0
收藏0
其他版本
除非特别说明，本系统中所有内容都受版权保护，并保留所有权利。