Head-to-Tail and Back-to-Back Dimerization of an Open-Cage Fullerene Derivative through pi-pi Interaction-Based Self-Assembly
文献类型：期刊论文
| 作者 | Liu, Shuming1,4; Zhang, Qianyan1; Yu, Yuming1; Gan, Liangbing1,2,3 |
| 刊名 | ORGANIC LETTERS
 |
| 出版日期 | 2012-08-03 |
| 卷号 | 14期号:15页码:4002-4005 |
| ISSN号 | 1523-7060 |
| DOI | 10.1021/ol301811p |
| 英文摘要 | Open-cage fullerene derivative 2, C-59(O)(4)(NAr)(2) (Ar = p-tBuC(6)H(4)), was prepared from 1, C-60(O)(4)(OH)(2)(NAr)(2), through processes involving decarbonylation and elimination of the two hydroxyl groups. The phenyl groups in compound 2 act as chelating ligands for the fullerene cage and induce partial dimerization of 2 in solution. The single crystal X-ray structure of 2 shows strong intradimer pi-pi interactions and also weaker interdimer CH-pi and pi-pi interactions. |
| 语种 | 英语 |
| WOS记录号 | WOS:000307041600049 |
| 出版者 | AMER CHEMICAL SOC |
| 源URL | [http://ir.iccas.ac.cn/handle/121111/49829]  |
| 专题 | 中国科学院化学研究所 |
| 通讯作者 | Gan, Liangbing |
| 作者单位 | 1.Chinese Acad Sci, Inst Chem, Beijing Natl Lab Mol Sci, CAS Key Lab Organ Solids, Beijing 100080, Peoples R China 2.Peking Univ, Coll Chem & Mol Engn, Minist Educ, Key Lab Bioorgan Chem & Mol Engn, Beijing 100871, Peoples R China 3.Shanghai Inst Organ Chem, State Key Lab Organometall Chem, Shanghai 200032, Peoples R China 4.Handan Coll, Dept Chem, Handan 056005, Peoples R China |
| 推荐引用方式 GB/T 7714 | Liu, Shuming,Zhang, Qianyan,Yu, Yuming,et al. Head-to-Tail and Back-to-Back Dimerization of an Open-Cage Fullerene Derivative through pi-pi Interaction-Based Self-Assembly[J]. ORGANIC LETTERS,2012,14(15):4002-4005. |
| APA | Liu, Shuming,Zhang, Qianyan,Yu, Yuming,&Gan, Liangbing.(2012).Head-to-Tail and Back-to-Back Dimerization of an Open-Cage Fullerene Derivative through pi-pi Interaction-Based Self-Assembly.ORGANIC LETTERS,14(15),4002-4005. |
| MLA | Liu, Shuming,et al."Head-to-Tail and Back-to-Back Dimerization of an Open-Cage Fullerene Derivative through pi-pi Interaction-Based Self-Assembly".ORGANIC LETTERS 14.15(2012):4002-4005. |
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来源：化学研究所
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