Yttrium Hydride Complex Bearing CpPN/Amidinate Heteroleptic Ligands: Synthesis, Structure, and Reactivity
文献类型：期刊论文
| 作者 | Jian, Zhongbao2,3; Hangaly, Noa K.1; Rong, Weifeng2,3; Mou, Zehuai2,3; Liu, Dongtao2; Li, Shihui2; Trifonov, Alexander A.5; Sundermeyer, Joerg1; Cui, Dongmei2,4 |
| 刊名 | ORGANOMETALLICS
 |
| 出版日期 | 2012-06-25 |
| 卷号 | 31期号:12页码:4579-4587 |
| ISSN号 | 0276-7333 |
| DOI | 10.1021/om3003703 |
| 英文摘要 | The reaction of the yttrium dialkyls (C5H4- PPh2=N (C6H3Pr2)-Pr-i)Y(CH2SiMe3)(2)(thf) (1) with an excess of N,N'-diisopropylcarbodiimide gave the yttrium monoalkyl complex (C5H4-PPh2=N-(C6H3Pr2)-Pr-i)Y(CH2SiMe3)[(PrN)-Pr-i= C(CH2SiMe3)-(NPr)-Pr-i] (2). 2 subsequently reacted with 1 equiv of PhSiH3 to generate the CpPN/amidinate heteroleptic yttrium hydride [(C5H4-PPh2=N (C6H3Pr2)-Pr-i)Y(CH2SiMe3)(2)-(NPr)-Pr-i](mu-H)}(2) (3). Hydride 3 showed good reactivity toward various substrates containing unsaturated C C, C-N, and N-N bonds, such as azobenzene, p-tolyacetylene, 1,4-bis(trimethylsily1)-1,3-butanediyne, N,N'-diisopropylcarbodiimide, and 4-dimethylaminopyridine, affording the yttrium hydrazide complex 4 with a rare eta(2)-Cp bonding mode, yttrium terminal alkynyl complex 5, yttrium eta(3)-propargyl complex 6, yttrium amidinate complex 7, and yttrium 2-hydro-4-dimethylaminopyridyl product 8, respectively. |
| 语种 | 英语 |
| WOS记录号 | WOS:000305588000025 |
| 出版者 | AMER CHEMICAL SOC |
| 源URL | [http://ir.iccas.ac.cn/handle/121111/49845]  |
| 专题 | 中国科学院化学研究所 |
| 通讯作者 | Sundermeyer, Joerg |
| 作者单位 | 1.Univ Marburg, Fachbereich Chem, D-35032 Marburg, Germany 2.Chinese Acad Sci, Changchun Inst Appl Chem, State Key Lab Polymer Phys & Chem, Changchun 130022, Peoples R China 3.Chinese Acad Sci, Grad Sch, Beijing 100039, Peoples R China 4.Chinese Acad Sci, Changchun Inst Appl Chem, State Key Lab Rare Earth Resources Utilizat, Changchun 130022, Peoples R China 5.Russian Acad Sci, GA Razuvaev Inst Organometall Chem, Nizhnii Novgorod 603950, Russia |
| 推荐引用方式 GB/T 7714 | Jian, Zhongbao,Hangaly, Noa K.,Rong, Weifeng,et al. Yttrium Hydride Complex Bearing CpPN/Amidinate Heteroleptic Ligands: Synthesis, Structure, and Reactivity[J]. ORGANOMETALLICS,2012,31(12):4579-4587. |
| APA | Jian, Zhongbao.,Hangaly, Noa K..,Rong, Weifeng.,Mou, Zehuai.,Liu, Dongtao.,...&Cui, Dongmei.(2012).Yttrium Hydride Complex Bearing CpPN/Amidinate Heteroleptic Ligands: Synthesis, Structure, and Reactivity.ORGANOMETALLICS,31(12),4579-4587. |
| MLA | Jian, Zhongbao,et al."Yttrium Hydride Complex Bearing CpPN/Amidinate Heteroleptic Ligands: Synthesis, Structure, and Reactivity".ORGANOMETALLICS 31.12(2012):4579-4587. |
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来源：化学研究所
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