Nanostructured Polyaniline-Decorated Pt/C@PANI Core-Shell Catalyst with Enhanced Durability and Activity
文献类型：期刊论文
| 作者 | Chen, Siguo1; Wei, Zidong1; Qi, XueQiang1; Dong, Lichun1; Guo, Yu-Guo2; Wan, Lijun2; Shao, Zhigang3; Li, Li1 |
| 刊名 | JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
 |
| 出版日期 | 2012-08-15 |
| 卷号 | 134期号:32页码:13252-13255 |
| ISSN号 | 0002-7863 |
| DOI | 10.1021/ja306501x |
| 英文摘要 | We have designed and synthesized a polyaniline (PANI)-decorated Pt/C@PANI core-shell catalyst that shows enhanced catalyst activity and durability compared with nondecorated Pt/C. The experimental results demonstrate that the activity for the oxygen reduction reaction strongly depends on the thickness of the PANI shell and that the greatest enhancement in catalytic properties occurs at a thickness of 5 nm, followed by 2.5, 0, and 14 nm. Pt/C@PANI also demonstrates significantly improved stability compared with that of the unmodified Pt/C catalyst. The high activity and stability of the Pt/C@PANI catalyst is ascribed to its novel PANI-decorated core shell structure, which induces both electron delocalization between the Pt d orbitals and the PANI pi-conjugated ligand and electron transfer from Pt to PANI. The stable PANT shell also protects the carbon support from direct exposure to the corrosive environment. |
| 语种 | 英语 |
| WOS记录号 | WOS:000307487200028 |
| 出版者 | AMER CHEMICAL SOC |
| 源URL | [http://ir.iccas.ac.cn/handle/121111/49875]  |
| 专题 | 中国科学院化学研究所 |
| 通讯作者 | Wei, Zidong |
| 作者单位 | 1.Chongqing Univ, Coll Chem & Chem Engn, State Key Lab Power Transmiss Equipment & Syst Se, Chongqing 400044, Peoples R China 2.Chinese Acad Sci, Inst Chem, Key Lab Mol Nanostruct & Nanotechnol, Beijing 100190, Peoples R China 3.Chinese Acad Sci, Dalian Inst Chem Phys, Dalian Liaoning 116023, Peoples R China |
| 推荐引用方式 GB/T 7714 | Chen, Siguo,Wei, Zidong,Qi, XueQiang,et al. Nanostructured Polyaniline-Decorated Pt/C@PANI Core-Shell Catalyst with Enhanced Durability and Activity[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY,2012,134(32):13252-13255. |
| APA | Chen, Siguo.,Wei, Zidong.,Qi, XueQiang.,Dong, Lichun.,Guo, Yu-Guo.,...&Li, Li.(2012).Nanostructured Polyaniline-Decorated Pt/C@PANI Core-Shell Catalyst with Enhanced Durability and Activity.JOURNAL OF THE AMERICAN CHEMICAL SOCIETY,134(32),13252-13255. |
| MLA | Chen, Siguo,et al."Nanostructured Polyaniline-Decorated Pt/C@PANI Core-Shell Catalyst with Enhanced Durability and Activity".JOURNAL OF THE AMERICAN CHEMICAL SOCIETY 134.32(2012):13252-13255. |
入库方式： OAI收割
来源：化学研究所
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