Formation of silica nanotubes through a TPPS J aggregates template
文献类型：期刊论文
| 作者 | Zhang Li1; Jiang Jian2; Liu MingHua1 |
| 刊名 | CHINESE SCIENCE BULLETIN
 |
| 出版日期 | 2012-11-01 |
| 卷号 | 57期号:33页码:4322-4327 |
| 关键词 | j Aggregates Sol-gel Transcription Silica Nanostructures |
| ISSN号 | 1001-6538 |
| DOI | 10.1007/s11434-012-5432-4 |
| 英文摘要 | It is found that 5,10,15,20-tetrakis (4-sulfonatophenyl) porphyrin (TPPS), which is known to form J aggregates in water under low pH value, acts as a template for the hydrolyzing of organosilane. The nanotube structures of silica with 4-8 nm inner diameters are obtained, which is consistent with the height of TPPS J aggregates, indicating that TPPS J aggregates are indeed acting as the template for the sol-gel transcription. The TPPS J aggregation disappear when the medium pH value is shifted from acidic to basic, consequently formed silica nanostructures are amorphous nanosphere rather than nanofiber structures. In contrast, the copper phthalocyanine (TSCuPc), which does not exist as linear J aggregates, cannot induce the silica to form one dimensional nanofiber structures, implying that the templating effect of TPPS J aggregates for inorganic nanostructures. |
| 语种 | 英语 |
| WOS记录号 | WOS:000310993200012 |
| 出版者 | SCIENCE PRESS |
| 源URL | [http://ir.iccas.ac.cn/handle/121111/49879]  |
| 专题 | 中国科学院化学研究所 |
| 通讯作者 | Zhang Li |
| 作者单位 | 1.Chinese Acad Sci, Beijing Natl Lab Mol Sci, Inst Chem, CAS Key Lab Colloid Interface & Chem Thermodynam, Beijing 100190, Peoples R China 2.Natl Ctr Nanosci & Technol, Beijing 100190, Peoples R China |
| 推荐引用方式 GB/T 7714 | Zhang Li,Jiang Jian,Liu MingHua. Formation of silica nanotubes through a TPPS J aggregates template[J]. CHINESE SCIENCE BULLETIN,2012,57(33):4322-4327. |
| APA | Zhang Li,Jiang Jian,&Liu MingHua.(2012).Formation of silica nanotubes through a TPPS J aggregates template.CHINESE SCIENCE BULLETIN,57(33),4322-4327. |
| MLA | Zhang Li,et al."Formation of silica nanotubes through a TPPS J aggregates template".CHINESE SCIENCE BULLETIN 57.33(2012):4322-4327. |
入库方式： OAI收割
来源：化学研究所
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