In situ synthesis of manganese(III) complexes under control: Crystal structure and magnetic properties
文献类型：期刊论文
| 作者 | Ding, Shuai1; Ji, Yu-Fei1; Kang, Min-Yan1; Du, Chun-Fang1; Liu, Zhi-Liang1; Liu, Cai-Ming2 |
| 刊名 | INORGANIC CHEMISTRY COMMUNICATIONS
 |
| 出版日期 | 2012-07-01 |
| 卷号 | 21页码:96-99 |
| 关键词 | Manganese(Iii) Complexes In Situ Synthesis Crystal Structure Magnetic Properties |
| ISSN号 | 1387-7003 |
| DOI | 10.1016/j.inoche.2012.04.022 |
| 英文摘要 | Three new manganese(III) compounds have been synthesized via in situ ligand transformation and oxidation of Mn(II) ions. In the presence/absence of N-3(-) anion in the reaction solutions, the dinuclear/mononuclear Mn(III) coordination compounds were formed, respectively. A structural analysis of the dinuclear compounds (1, 2) shows that the six coordination Mn(III) atoms are linked by two methanolato oxygen atoms from two ligands to form a rectangular arrangement of the metal ions and oxygen atoms. In complex 3, two facially coordinating tridentate ligands are bound to the Mn(III) ion, resulting in a MnN4O2 chromophore with an axially-compressed octahedral geometry. In addition, variable-temperature magnetic analysis of 1 shows that a weak antiferromagnetic coupling interaction was mediated through the methanolato oxygen bridge between two Mn(III) ions and the exchange parameter is given as J = 3.6 cm(-1). (C) 2012 Elsevier B.V. All rights reserved. |
| 语种 | 英语 |
| WOS记录号 | WOS:000306614900026 |
| 出版者 | ELSEVIER SCIENCE BV |
| 源URL | [http://ir.iccas.ac.cn/handle/121111/49921]  |
| 专题 | 中国科学院化学研究所 |
| 通讯作者 | Liu, Zhi-Liang |
| 作者单位 | 1.Inner Mongolia Univ, Coll Chem & Chem Engn, Hohhot 010021, Peoples R China 2.Chinese Acad Sci, Inst Chem, Ctr Mol Sci, Lab Organ Solids, Beijing 100190, Peoples R China |
| 推荐引用方式 GB/T 7714 | Ding, Shuai,Ji, Yu-Fei,Kang, Min-Yan,et al. In situ synthesis of manganese(III) complexes under control: Crystal structure and magnetic properties[J]. INORGANIC CHEMISTRY COMMUNICATIONS,2012,21:96-99. |
| APA | Ding, Shuai,Ji, Yu-Fei,Kang, Min-Yan,Du, Chun-Fang,Liu, Zhi-Liang,&Liu, Cai-Ming.(2012).In situ synthesis of manganese(III) complexes under control: Crystal structure and magnetic properties.INORGANIC CHEMISTRY COMMUNICATIONS,21,96-99. |
| MLA | Ding, Shuai,et al."In situ synthesis of manganese(III) complexes under control: Crystal structure and magnetic properties".INORGANIC CHEMISTRY COMMUNICATIONS 21(2012):96-99. |
入库方式： OAI收割
来源：化学研究所
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