Triphenylamine modified bis-diketopyrrolopyrrole molecular donor materials with extended conjugation for bulk heterojunction solar cells
文献类型：期刊论文
| 作者 | Feng, Hai-Fen1; Fu, Wei-Fei2,3; Li, Liangjie4; Yu, Qing-Cai1; Lu, Hua1; Wan, Jun-Hua1; Shi, Min-Min2,3; Chen, Hong-Zheng2,3; Tan, Zhan'ao4; Li, Yongfang5 |
| 刊名 | ORGANIC ELECTRONICS
 |
| 出版日期 | 2014-10-01 |
| 卷号 | 15期号:10页码:2575-2586 |
| 关键词 | Organic Solar Cell Solution-processable Small Molecule Triphenylamine Diketopyrrolopyrrole Donor-acceptor |
| ISSN号 | 1566-1199 |
| DOI | 10.1016/j.orgel.2014.07.020 |
| 英文摘要 | Two new solution-processable enlarged pi -conjugated donor-acceptor (D-A) organic small molecules consisting of dialkoxysubstituted benzo[1,2-b:4,5-b'] dithiophene (BDT) or dioctyltertthiophene (3T) as the central donor units, diketopyrrolopyrrole (DPP) as the acceptor unit and triphenylamine (TPA) as the terminal conjugated segment, TPA-DPP-BDT and TPA-DPP-3T, were designed and synthesized. Both small molecules possess broad absorption ranging from 300 to 800 nm with an optical band at approximately 1.50 eV and relatively low HOMO energy levels from -5.12 to approximately -5.16 eV. Expectedly, the UV-Vis absorption onset (810 nm) of TPA-DPP-BDT is largely red-shifted (60 nm) relative to that (750 nm) of previously reported BDT(TDPP) 2, which consists of BDT and DPP units. Unlike most of the TPA based molecules, strong molecular aggregation was observed in the solid state for both small molecules. In addition, atomic force microscopy (AFM) and X-ray diffraction (XRD) investigations indicated that TPA-DPP-3T and TPA-DPP-BDT exhibit good miscibility with fullerene derivatives. The organic solar cells based on TPA-DPP-BDT/PC61BM(1:1) demonstrated power conversion efficiencies as high as 4.04% with a short-circuit current density (J(sc)) of 11.40 mA cm (2) and a fill factor (FF) of 53.2% when the active layer of the cell was annealed at 130 degrees C for 10 min. (C) 2014 Elsevier B.V. All rights reserved. |
| 语种 | 英语 |
| WOS记录号 | WOS:000341290000055 |
| 出版者 | ELSEVIER SCIENCE BV |
| 源URL | [http://ir.iccas.ac.cn/handle/121111/49957]  |
| 专题 | 中国科学院化学研究所 |
| 通讯作者 | Wan, Jun-Hua |
| 作者单位 | 1.Hangzhou Normal Univ, Minist Educ, Key Lab Organosilicon Chem & Mat Technol, Hangzhou 310012, Zhejiang, Peoples R China 2.Zhejiang Univ, MOE Key Lab Macromol Synth & Functionalizat, State Key Lab Silicon Mat, Hangzhou 310027, Zhejiang, Peoples R China 3.Zhejiang Univ, Dept Polymer Sci & Engn, Hangzhou 310027, Zhejiang, Peoples R China 4.North China Elect Power Univ, New & Renewable Energy Beijing Key Lab Sch Renewa, Beijing 102206, Peoples R China 5.Chinese Acad Sci, Inst Chem, Beijing Natl Lab Mol Sci, Beijing 100190, Peoples R China |
| 推荐引用方式 GB/T 7714 | Feng, Hai-Fen,Fu, Wei-Fei,Li, Liangjie,et al. Triphenylamine modified bis-diketopyrrolopyrrole molecular donor materials with extended conjugation for bulk heterojunction solar cells[J]. ORGANIC ELECTRONICS,2014,15(10):2575-2586. |
| APA | Feng, Hai-Fen.,Fu, Wei-Fei.,Li, Liangjie.,Yu, Qing-Cai.,Lu, Hua.,...&Li, Yongfang.(2014).Triphenylamine modified bis-diketopyrrolopyrrole molecular donor materials with extended conjugation for bulk heterojunction solar cells.ORGANIC ELECTRONICS,15(10),2575-2586. |
| MLA | Feng, Hai-Fen,et al."Triphenylamine modified bis-diketopyrrolopyrrole molecular donor materials with extended conjugation for bulk heterojunction solar cells".ORGANIC ELECTRONICS 15.10(2014):2575-2586. |
入库方式： OAI收割
来源：化学研究所
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