Concurrent Oxidation of Alcohols and the Passerini Three-Component Polymerization for the Synthesis of Functional Poly(ester amide)s
文献类型：期刊论文
| 作者 | Kan, Xiao-Wei; Deng, Xin-Xing; Du, Fu-Sheng; Li, Zi-Chen |
| 刊名 | MACROMOLECULAR CHEMISTRY AND PHYSICS
 |
| 出版日期 | 2014-11-01 |
| 卷号 | 215期号:22页码:2221-2228 |
| 关键词 | Cascade Process Multicomponent Polymerization Oxidation Passerini Reaction Poly(Ester Amide) |
| ISSN号 | 1022-1352 |
| DOI | 10.1002/macp.201400264 |
| 英文摘要 | A new polymerization method based on the Passerini three-component reaction of a dicarboxylic acid, an alcohol, and a diisocyanide in the presence of an oxidant is reported. This polymerization involves the concurrent oxidation of alcohols by o-iodoxybenzoic acid (IBX) and the Passerini three-component polymerization. The kinetics of the alcohol oxidation and the Passerini reaction are investigated, and the results indicate that the cascade process can occur efficiently. The reaction conditions are optimized, and various functional alcohols are examined to get insight into the applicability of the method. Based on the optimized conditions, a variety of functional poly(ester amide)s are prepared in a one-pot fashion via using 1,6-diisocyanohexane, 1,6-hexanedioic acid, different functional alcohols, and iodoxybenzoic acid. The introduction of functional pendant groups, especially alkynyl, alkenyl and epoxy groups, to the final poly(ester amide) s, provides an efficient way for further modification of the polymers. |
| 语种 | 英语 |
| WOS记录号 | WOS:000345444200008 |
| 出版者 | WILEY-V C H VERLAG GMBH |
| 源URL | [http://ir.iccas.ac.cn/handle/121111/50021]  |
| 专题 | 中国科学院化学研究所 |
| 通讯作者 | Li, Zi-Chen |
| 作者单位 | Peking Univ, Coll Chem & Mol Engn, Dept Polymer Sci & Engn, BNLMS,Key Lab Polymer Chem & Phys,Minist Educ, Beijing 100871, Peoples R China |
| 推荐引用方式 GB/T 7714 | Kan, Xiao-Wei,Deng, Xin-Xing,Du, Fu-Sheng,et al. Concurrent Oxidation of Alcohols and the Passerini Three-Component Polymerization for the Synthesis of Functional Poly(ester amide)s[J]. MACROMOLECULAR CHEMISTRY AND PHYSICS,2014,215(22):2221-2228. |
| APA | Kan, Xiao-Wei,Deng, Xin-Xing,Du, Fu-Sheng,&Li, Zi-Chen.(2014).Concurrent Oxidation of Alcohols and the Passerini Three-Component Polymerization for the Synthesis of Functional Poly(ester amide)s.MACROMOLECULAR CHEMISTRY AND PHYSICS,215(22),2221-2228. |
| MLA | Kan, Xiao-Wei,et al."Concurrent Oxidation of Alcohols and the Passerini Three-Component Polymerization for the Synthesis of Functional Poly(ester amide)s".MACROMOLECULAR CHEMISTRY AND PHYSICS 215.22(2014):2221-2228. |
入库方式： OAI收割
来源：化学研究所
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