Structure and Magnetic Properties of a Trinuclear Nickel(II) Complex Constructed by bpca(-) Anions
文献类型：期刊论文
| 作者 | Huang, Ximing1; Fan, Chunhua1; Lu, Jing2; Liu, Cai-Ming3; Lu, Zhengliang1; Nie, Yong1 |
| 刊名 | ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE
 |
| 出版日期 | 2014-10-01 |
| 卷号 | 640期号:12-13页码:2439-2443 |
| 关键词 | Self-assembly Hbpca Transition Metal Magnetic Properties Crystal Structure |
| ISSN号 | 0044-2313 |
| DOI | 10.1002/zaac.201400184 |
| 英文摘要 | The trinuclear Ni-II cluster [Ni-3(bpca)(2)(bpy)(2)(H2O)(4)](NO3)(4)center dot H2O (1) (bpca(-) = anion of bis(2-pyridylcarbonyl)amine, bpy = 2,2'-bipyridine) was isolated. Single crystal X-ray diffraction analysis showed that three crystallographically independent Ni-II ions are located in a six-coordinate distorted octahedral environment, bridged by the organic spacer bpca(-). The crystal lattice is stabilized by hydrogen bonds, which are linking the Ni-3 cations and NO3- anions into a three-dimensional framework. Variable-temperature magnetic susceptibility for complex 1 in the range 2-300 K indicates the presence of weak antiferromagnetic interactions in the Ni-3 unit with J = -0.67 cm(-1). |
| 语种 | 英语 |
| WOS记录号 | WOS:000344378900004 |
| 出版者 | WILEY-V C H VERLAG GMBH |
| 源URL | [http://ir.iccas.ac.cn/handle/121111/50039]  |
| 专题 | 中国科学院化学研究所 |
| 通讯作者 | Fan, Chunhua |
| 作者单位 | 1.Univ Jinan, Sch Chem & Chem Engn, Jinan 250022, Peoples R China 2.Liaocheng Univ, Sch Chem & Chem Engn, Shandong Prov Key Lab Chem Energy Storage & Cell, Liaocheng 252059, Peoples R China 3.Chinese Acad Sci, Key Lab Organ Solids, Inst Chem, Beijing Natl Lab Mol Sci,Ctr Mol Sci, Beijing 100190, Peoples R China |
| 推荐引用方式 GB/T 7714 | Huang, Ximing,Fan, Chunhua,Lu, Jing,et al. Structure and Magnetic Properties of a Trinuclear Nickel(II) Complex Constructed by bpca(-) Anions[J]. ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE,2014,640(12-13):2439-2443. |
| APA | Huang, Ximing,Fan, Chunhua,Lu, Jing,Liu, Cai-Ming,Lu, Zhengliang,&Nie, Yong.(2014).Structure and Magnetic Properties of a Trinuclear Nickel(II) Complex Constructed by bpca(-) Anions.ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE,640(12-13),2439-2443. |
| MLA | Huang, Ximing,et al."Structure and Magnetic Properties of a Trinuclear Nickel(II) Complex Constructed by bpca(-) Anions".ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE 640.12-13(2014):2439-2443. |
入库方式： OAI收割
来源：化学研究所
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