New Morphologies and Phase Transitions of Rod-Coil Dendritic-Linear Block Copolymers Depending on Dendron Generation and Preparation Procedure
文献类型：期刊论文
| 作者 | Cai, Huanhuan1; Jiang, Guoliang1; Chen, Chongyi2; Li, Zhibo2; Shen, Zhihao1; Fan, Xinghe1 |
| 刊名 | MACROMOLECULES
 |
| 出版日期 | 2014-01-14 |
| 卷号 | 47期号:1页码:146-151 |
| ISSN号 | 0024-9297 |
| DOI | 10.1021/ma402112n |
| 英文摘要 | Amphiphilic rod coil dendritic linear block copolymers PEG(G(m))-b-PMPCS (where m is the number of dendron generation, and m = 1, 2, 3) composed of a semirigid Percec-type dendron with hydrophilic poly(ethylene glycol) (PEG) tails and a rodlike mesogen-jacketed liquid crystalline polymer, poly{2,5-bis[(4'-methoxy-phenyl)oxycarbonyl]styrene} (PMPCS), were successfully prepared. The self-assembled structures undergo a transition from vesicles through large compound vesicles (LCVs) to short cylindrical micelles with increasing dendron generation. PEG(G(2))-b-PMPCS forms stable LCVs with porous surfaces of a narrow size distribution in a mixed solvent of tetrahydrofuran and water. The formation mechanism of the supramolecular structure with nano- and microsized scales is studied through changing the rate of water addition. It is composed of two steps: morphological transformation and vesicles fusion or differentiation. Vesicles are precursors for LCVs regardless of what the initial morphology is. However, the final LCV structures are different. Slow addition of water produces spherical LCVs, while those formed during fast water addition are irregular (like deformed spherical) LCVs. |
| 语种 | 英语 |
| WOS记录号 | WOS:000330001700018 |
| 出版者 | AMER CHEMICAL SOC |
| 源URL | [http://ir.iccas.ac.cn/handle/121111/50059]  |
| 专题 | 中国科学院化学研究所 |
| 通讯作者 | Shen, Zhihao |
| 作者单位 | 1.Peking Univ, Coll Chem & Mol Engn, Beijing Natl Lab Mol Sci, Key Lab Polymer Chem & Phys,Minist Educ, Beijing 100871, Peoples R China 2.Chinese Acad Sci, Inst Chem, Lab Polymer Phys & Chem, Beijing 100190, Peoples R China |
| 推荐引用方式 GB/T 7714 | Cai, Huanhuan,Jiang, Guoliang,Chen, Chongyi,et al. New Morphologies and Phase Transitions of Rod-Coil Dendritic-Linear Block Copolymers Depending on Dendron Generation and Preparation Procedure[J]. MACROMOLECULES,2014,47(1):146-151. |
| APA | Cai, Huanhuan,Jiang, Guoliang,Chen, Chongyi,Li, Zhibo,Shen, Zhihao,&Fan, Xinghe.(2014).New Morphologies and Phase Transitions of Rod-Coil Dendritic-Linear Block Copolymers Depending on Dendron Generation and Preparation Procedure.MACROMOLECULES,47(1),146-151. |
| MLA | Cai, Huanhuan,et al."New Morphologies and Phase Transitions of Rod-Coil Dendritic-Linear Block Copolymers Depending on Dendron Generation and Preparation Procedure".MACROMOLECULES 47.1(2014):146-151. |
入库方式： OAI收割
来源：化学研究所
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