Uniaxial Movements of a Metal-Cyanide Framework Switched by Weak Interactions through Dehydration and Rehydration
文献类型：期刊论文
| 作者 | Wei, Bin1; Shang, Ran2; Zhang, Xi3,4; Shao, Xiu-Dan1; Yao, Ye-Feng3,4; Wang, Zhe-Ming2; Xiong, Ren-Gen1; Zhang, Wen1 |
| 刊名 | CHEMISTRY-A EUROPEAN JOURNAL
 |
| 出版日期 | 2014-07-01 |
| 卷号 | 20期号:27页码:8269-8273 |
| 关键词 | Crystal Engineering Cyanide Dehydration-rehydration Iron Metal-organic Frameworks |
| ISSN号 | 0947-6539 |
| DOI | 10.1002/chem.201402892 |
| 英文摘要 | A metal-cyanide framework undergoes a dehydration-rehydration triggered reversible single-crystal-to-single-crystal transformation. The resulting accordion-like contraction-expansion corresponds to a size change along the c axis as much as 24%. This anisotropic response arises from the cooperativity among the water molecules, K ions, and CN groups between the unique two-dimensional bimetallic layers through weak interactions of hydrogen bonds and electrostatic (ionic) interactions. The key role of the water molecules in the dehydration-rehydration process is revealed by solid-state H-1 NMR spectroscopy and dielectric measurements. |
| 语种 | 英语 |
| WOS记录号 | WOS:000338019300004 |
| 出版者 | WILEY-V C H VERLAG GMBH |
| 源URL | [http://ir.iccas.ac.cn/handle/121111/50161]  |
| 专题 | 中国科学院化学研究所 |
| 通讯作者 | Yao, Ye-Feng |
| 作者单位 | 1.Southeast Univ, Ordered Matter Sci Res Ctr, Nanjing 211189, Jiangsu, Peoples R China 2.Peking Univ, Beijing Natl Lab Mol Sci, State Key Lab Rare Earth Mat Chem & Applicat, Coll Chem & Mol Engn, Beijing 100871, Peoples R China 3.E China Normal Univ, Dept Phys, Shanghai 200062, Peoples R China 4.E China Normal Univ, Shanghai Key Lab Magnet Resonance, Shanghai 200062, Peoples R China |
| 推荐引用方式 GB/T 7714 | Wei, Bin,Shang, Ran,Zhang, Xi,et al. Uniaxial Movements of a Metal-Cyanide Framework Switched by Weak Interactions through Dehydration and Rehydration[J]. CHEMISTRY-A EUROPEAN JOURNAL,2014,20(27):8269-8273. |
| APA | Wei, Bin.,Shang, Ran.,Zhang, Xi.,Shao, Xiu-Dan.,Yao, Ye-Feng.,...&Zhang, Wen.(2014).Uniaxial Movements of a Metal-Cyanide Framework Switched by Weak Interactions through Dehydration and Rehydration.CHEMISTRY-A EUROPEAN JOURNAL,20(27),8269-8273. |
| MLA | Wei, Bin,et al."Uniaxial Movements of a Metal-Cyanide Framework Switched by Weak Interactions through Dehydration and Rehydration".CHEMISTRY-A EUROPEAN JOURNAL 20.27(2014):8269-8273. |
入库方式： OAI收割
来源：化学研究所
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