Rhodium(III)-Catalyzed ortho Alkenylation of N-Phenoxyacetamides with N-Tosylhydrazones or Diazoesters through C-H Activation
文献类型：期刊论文
| 作者 | Hu, Fangdong1,2,3; Xia, Ying1,2; Ye, Fei1,2; Liu, Zhenxing1,2; Ma, Chen1,2,3; Zhang, Yan1,2; Wang, Jianbo1,2 |
| 刊名 | ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
 |
| 出版日期 | 2014-01-27 |
| 卷号 | 53期号:5页码:1364-1367 |
| 关键词 | C-h Activation Diazo Compounds Homogeneous Catalysis Metal-carbene Complexes Migratory Insertion |
| ISSN号 | 1433-7851 |
| DOI | 10.1002/anie.201309650 |
| 英文摘要 | A coupling reaction of N-phenoxyacetamides with N-tosylhydrazones or diazoesters through Rh-III-catalyzed C-H activation is reported. In this reaction, ortho-alkenyl phenols were obtained in good yields and with excellent regio- and stereoselectivity. Rh-carbene migratory insertion is proposed as the key step in the reaction mechanism. |
| 语种 | 英语 |
| WOS记录号 | WOS:000336504500031 |
| 出版者 | WILEY-V C H VERLAG GMBH |
| 源URL | [http://ir.iccas.ac.cn/handle/121111/50233]  |
| 专题 | 中国科学院化学研究所 |
| 通讯作者 | Wang, Jianbo |
| 作者单位 | 1.Peking Univ, Coll Chem, BNLMS, Beijing 100871, Peoples R China 2.Peking Univ, Coll Chem, Key Lab Bioorgan Chem & Mol Engn, Minist Educ, Beijing 100871, Peoples R China 3.Shandong Univ, Sch Chem & Chem Engn, Jinan 250100, Peoples R China |
| 推荐引用方式 GB/T 7714 | Hu, Fangdong,Xia, Ying,Ye, Fei,et al. Rhodium(III)-Catalyzed ortho Alkenylation of N-Phenoxyacetamides with N-Tosylhydrazones or Diazoesters through C-H Activation[J]. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION,2014,53(5):1364-1367. |
| APA | Hu, Fangdong.,Xia, Ying.,Ye, Fei.,Liu, Zhenxing.,Ma, Chen.,...&Wang, Jianbo.(2014).Rhodium(III)-Catalyzed ortho Alkenylation of N-Phenoxyacetamides with N-Tosylhydrazones or Diazoesters through C-H Activation.ANGEWANDTE CHEMIE-INTERNATIONAL EDITION,53(5),1364-1367. |
| MLA | Hu, Fangdong,et al."Rhodium(III)-Catalyzed ortho Alkenylation of N-Phenoxyacetamides with N-Tosylhydrazones or Diazoesters through C-H Activation".ANGEWANDTE CHEMIE-INTERNATIONAL EDITION 53.5(2014):1364-1367. |
入库方式： OAI收割
来源：化学研究所
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