中国科学院机构知识库网格
Chinese Academy of Sciences Institutional Repositories Grid
Synthesis and Properties of Biodegradable Multiblock Poly(ester-carbonate) Comprising of Poly(L-lactic acid) and Poly(butylene carbonate) with Hexamethylene Diisocyanate as Chain-Extender

文献类型:期刊论文

作者Wang, Jin1,2; Zheng, Liuchun1; Li, Chuncheng1; Zhu, Wenxiang1; Zhang, Dong1; Guan, Guohu1; Xiao, Yaonan1
刊名JOURNAL OF APPLIED POLYMER SCIENCE
出版日期2014-03-05
卷号131期号:5
ISSN号0021-8995
关键词Biodegradable BioPolymers And Renewable Polymers Copolymers
DOI10.1002/app.39158
英文摘要A series of novel biodegradable poly(ester-carbonate) consisting of poly(L-lactic acid) (PLLA) and poly(butylene carbonate) (PBC) (PLLA-b-PBC) have been successfully synthesized by chain-extension reaction of dihydroxyl-terminated poly(L-lactic acid) prepolymer (PLLA-OH) and dihydroxyl-terminated poly(butylene carbonate) prepolymer (PBC-OH) using hexamethylene diisocyanate as a chain-extender. The chemical structures and molecular weights of copolymers are characterized by H-1 NMR and gel permeation chromatography. The thermal properties, morphology, and mechanical properties of PLLA-b-PBC are investigated by differential scanning calorimetry, thermogravimetric analysis, phase contrast optical microscopy, and mechanical testing. The results indicate that PBC soft segment slightly increases the thermal stabilities and effectively enhances the impact strength of the copolymers. (c) 2013 Wiley Periodicals, Inc. J. Appl. Polym. Sci., 2014, 131, 39158.
语种英语
出版者WILEY-BLACKWELL
WOS记录号WOS:000335233500007
源URL[http://ir.iccas.ac.cn/handle/121111/50235]  
专题中国科学院化学研究所
通讯作者Li, Chuncheng
作者单位1.Chinese Acad Sci ICCAS, Beijing Natl Lab Mol Sci, Key Lab Engn Plast, Inst Chem, Beijing 100190, Peoples R China
2.Yunnan Acad Tobacco Sci, Key Lab Tobacco Chem Yunnan Prov, Kunming 650106, Peoples R China
推荐引用方式
GB/T 7714
Wang, Jin,Zheng, Liuchun,Li, Chuncheng,et al. Synthesis and Properties of Biodegradable Multiblock Poly(ester-carbonate) Comprising of Poly(L-lactic acid) and Poly(butylene carbonate) with Hexamethylene Diisocyanate as Chain-Extender[J]. JOURNAL OF APPLIED POLYMER SCIENCE,2014,131(5).
APA Wang, Jin.,Zheng, Liuchun.,Li, Chuncheng.,Zhu, Wenxiang.,Zhang, Dong.,...&Xiao, Yaonan.(2014).Synthesis and Properties of Biodegradable Multiblock Poly(ester-carbonate) Comprising of Poly(L-lactic acid) and Poly(butylene carbonate) with Hexamethylene Diisocyanate as Chain-Extender.JOURNAL OF APPLIED POLYMER SCIENCE,131(5).
MLA Wang, Jin,et al."Synthesis and Properties of Biodegradable Multiblock Poly(ester-carbonate) Comprising of Poly(L-lactic acid) and Poly(butylene carbonate) with Hexamethylene Diisocyanate as Chain-Extender".JOURNAL OF APPLIED POLYMER SCIENCE 131.5(2014).

入库方式: OAI收割

来源:化学研究所

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