Finding the Lost Open-Circuit Voltage in Polymer Solar Cells by UV-Ozone Treatment of the Nickel Acetate Anode Buffer Layer
文献类型：期刊论文
| 作者 | Wang, Fuzhi1; Sun, Gang1; Li, Cong1; Liu, Jiyan3; Hu, Siqian3; Zheng, Hua4; Tan, Zhan'ao1; Li, Yongfang2 |
| 刊名 | ACS APPLIED MATERIALS & INTERFACES
 |
| 出版日期 | 2014-06-25 |
| 卷号 | 6期号:12页码:9458-9465 |
| 关键词 | Polymer Solar Cells Anode Buffer Layer Nickel Acetate Uv-ozone Treatment |
| ISSN号 | 1944-8244 |
| DOI | 10.1021/am5017705 |
| 英文摘要 | Efficient polymer solar cells (PSCs) with enhanced open-circuit voltage (V-oc) are fabricated by introducing solution-processed and UV-ozone (UVO)-treated nickel acetate (O-NiAc) as an anode buffer layer. According to X-ray photoelectron spectroscopy data, NiAc partially decomposed to NiOOH during the UVO treatment. NiOOH is a dipole species, which leads to an increase in the work function (as confirmed by ultraviolet photoemission spectroscopy), thus benefitting the formation of ohmic contact between the anode and photoactive layer and leading to increased V-oc. In addition, the UVO treatment improves the wettability between the substrate and solvent of the active layer, which facilitates the formation of an upper photoactive layer with better morphology. Further, the O-NiAc layer can decrease the series resistance (R-s) and increase the parallel resistance (R-p) of the devices, inducing enhanced V-oc in comparison with the as-prepared NiAc-buffered control devices without UVO treatment. For PSCs based on the P3HT:PCBM system, V-oc increases from 0.50 to 0.60 V after the NiAc buffer layer undergoes UVO treatment. Similarly, in the P3HT:ICBA system, the V-oc value of the device with a UVO-treated NiAc buffer layer increases from 0.78 to 0.88 V, showing an enhanced power conversion efficiency of 6.64%. |
| 语种 | 英语 |
| WOS记录号 | WOS:000338184500066 |
| 出版者 | AMER CHEMICAL SOC |
| 源URL | [http://ir.iccas.ac.cn/handle/121111/50257]  |
| 专题 | 中国科学院化学研究所 |
| 通讯作者 | Tan, Zhan'ao |
| 作者单位 | 1.North China Elect Power Univ, State Key Lab Alternate Elect Power Syst Renewabl, Beijing Key Lab Energy Secur & Clean Utilizat, Beijing 102206, Peoples R China 2.Chinese Acad Sci, Beijing Natl Lab Mol Sci, Inst Chem, Beijing 100190, Peoples R China 3.Jianghan Univ, Key Lab Optoelect Chem Mat & Devices, Minist Educ, Wuhan 430056, Peoples R China 4.Wuhan Univ Technol, Sch Chem Engn, Wuhan 430070, Peoples R China |
| 推荐引用方式 GB/T 7714 | Wang, Fuzhi,Sun, Gang,Li, Cong,et al. Finding the Lost Open-Circuit Voltage in Polymer Solar Cells by UV-Ozone Treatment of the Nickel Acetate Anode Buffer Layer[J]. ACS APPLIED MATERIALS & INTERFACES,2014,6(12):9458-9465. |
| APA | Wang, Fuzhi.,Sun, Gang.,Li, Cong.,Liu, Jiyan.,Hu, Siqian.,...&Li, Yongfang.(2014).Finding the Lost Open-Circuit Voltage in Polymer Solar Cells by UV-Ozone Treatment of the Nickel Acetate Anode Buffer Layer.ACS APPLIED MATERIALS & INTERFACES,6(12),9458-9465. |
| MLA | Wang, Fuzhi,et al."Finding the Lost Open-Circuit Voltage in Polymer Solar Cells by UV-Ozone Treatment of the Nickel Acetate Anode Buffer Layer".ACS APPLIED MATERIALS & INTERFACES 6.12(2014):9458-9465. |
入库方式： OAI收割
来源：化学研究所
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